A crystal (also called a "grain") is made up of one or more elements or compounds whose atoms or molecules are placed in repeating sequences, so that inside a single crystal of the material the structure in one place is virtually identical to that in another, except for any imperfections or irregularities like missing atoms, extra atoms, twisted crystals where entire planes of atoms are missing or extra planes wedged into the crystal, and dirt mixed into the crystal - there are even crystals that have other crystals imbedded in them or that are formed by mixtures of other crystals. It is these embedded/mixed crystals that are the major forms of crystals in steel and cast iron and give these metals their many properties. Each repeating building block or structure is a "cell" and the entire crystal is made up of these cells repeating themselves many millions of times. Each crystal starts a some point where a "seed" makes that point somehow different from the surrounding material in such a way that it is slightly easier for the atoms of Iron and/or other element or compound to grab onto an adjacent atom or molecule and begin weaving the crystal structure outward until it runs up against the edge of the object or up against other similar crystals that are also growing outward from "seeds." Note that a seed can be almost anything, but that it is necessary to have a seed to start a crystal; if not, it is possible to super-cool a material well below the temperature that the material normally forms the crystals at and the material will still remain in its original state until something happens to force a point in the material to change its properties enough to act as a seed, at which time a very rapid crystallization will occur, sometimes allowing unusual properties not present when the material forms its crystals immediately at the time that the temperature went below the crystal-forming critical temperature. A rapid drop in temperature that is much faster than the rate of crystal formation can cause a similar effect, which is the primary method to harden Iron with Carbon.

The crystals that form are not oriented between themselves and are tilted and/or offset from each other in every possible manner. This, plus the fact that there will usually be small gaps, dirt, excess Carbon, and so forth at the edges of Iron crystals, makes the strength of the crystal internally usually much higher than the binding strength between separate, adjacent crystals. Therefore, making any kind of failure process of the material have to pass through as many different crystals as possible by reducing the size of the average crystal will toughen and strengthen the material markedly. Alternatively, making the crystals large so that they have the least number of boundaries that a crack or tear must jump across to split the material apart, will weaken the material and render it more brittle. If the crystals are made round, then the material will be rather soft, since the crystals can move past each other easily. If the crystals are irregular in shape and size, then some spots will be stress points where the crystals are pressing harder against one-another and some places on the crystal that are sticking out are liable to break off, reducing the strength compared to a force that must pass through the maximum volume of each crystal; both factors making the material much more brittle. If a kind of crystal is excessively hard and brittle, mixing it in the proper way with tough and ductile crystals can combine the best of both types and result in a material better than either one by itself. Therefore, by selecting the kinds of crystals properly and interlocking them in the optimum manner, many different properties can be achieved in Iron and steel alloys from the same basic building blocks. Actually doing this took many years of hard, trial-and-error work during the 19th and 20th Centuries and new steel manufacturing methods are being developed to this day.

The various defects in a crystal are formed, deleted, changed, and moved about during heat treatment and mechanical working and these imperfections give Iron alloys many of their best (and worst) properties. In fact, the reason a yield point exists is that these defects move as a crystal deforms and tend to jam together, locking their atoms in place, until the force gets strong enough to tear them free - each tiny crystal thus deforms in small jumps, being locked into a fixed shape in-between. Ductile failure is smooth only when viewed at a distance. A metal object made from a single perfect crystal would have properties different from the same object made using the regular compositions, forms, and sizes of crystals now in use. Crystals near the boundary conditions where they form or dissolve (depending on the direction of changing temperature) will grow until they run into one-another and then they will continue to grow by cannibalizing each other - one crystal stripping adjacent crystals of their atoms and adding them to its outer edge - until, theoretically, a single huge crystal could form, though very slowly in most cases (small single-crystal metal objects, such as jet engine compressor blades, are manufactured today due to special techniques that speed up crystal growth, but limit it to only the "seed" that the manufacturer has put into the mold to start the crystallization process). This crystal growth is another limitation put on the time that certain heat treatments can be applied, if crystals of the wrong size are not to result. The effects of alloying elements on this factor, such as slowing or speeding up this process, is another reason that they are used.

Ferrite

Body-centered cubic structure. This means that each of its cells is composed of a cube of eight Iron atoms in the corners, with a ninth Iron atom in the exact center of the cube. Each corner Iron atom is the corner of seven more adjacent cells (except if the atom is at the edge of the crystal) and these cells stretch in all directions until the edge of the crystal is reached. This structure is very isotropic (the same strength in all directions) and the Iron atoms merely reform new cells if the crystal is deformed and any existing cells are broken, allowing the crystal to be very tough (in the sense of being crack-resistent>, not in the sense of being hard to deform, since wrought iron, which is almost all ferrite, is relatively easily pulled apart) and ductile and only split apart when the deformation physically separates one part of the crystal from another part, which merely results in two smaller, stretched ferrite crystals where one existed before. Brinell hardness of about 80-100, depending on crystal size/shape. Can internally contain up to 0.025% Carbon at 723°C, but none at room temperature.

Austenite

Face-centered cubic structure. This means that eight Iron atoms make up the corners of each cell, as in ferrite, but the center is empty, allowing small atoms like Carbon to fit inside, though when one does it enlarges the cell somewhat and makes the similar openings in adjacent cells more tightly closed, limiting the number of Carbon atoms allowed inside to a maximum of 0.8% of the total weight of the metal at 723°C and a maximum of 2% at 1130°C due to the thermal expansion of the metal opening the cell holes enough for more Carbon to fit before they squeeze close the remaining holes. Instead, each of the six sides of the cell has a fifth Iron atom at its center in an "X" pattern, so the cell contains 14 Iron atoms rather than nine (fewer cells per volume of crystal than ferrite) and the cells are each somewhat larger (further reducing the number of cells per volume of crystal). This crystal is the densest form of Iron. The crystal is just as isotropic as ferrite, but it only exists normally at a higher temperature, so it is even more ductile. Many steel mechanical working processes are done to Iron in its austenite phase since only here is it soft enough due to the elevated temperature to do so. Brinell hardness of about 110 (estimated).

Cementite

A compound of Iron and Carbon, Fe₃C, formed by internal pressure when austenite turns into ferrite and it will eventually turn back into ferrite or austenite and free Carbon if it can, though it can remain stable for a time inside austenite at just above the CHT (the higher the temperature, the faster it breaks down into austenite and Carbon). At below the CHT, it can remain stable indefinitely in most cases, though some forms of Iron will gradually "age" and change their internal structure as they undergo stresses from their own weight or from applied forces as they are used. Contains 6.7% Carbon by weight. Each cell is made up of a triangular pyramid with the three Iron atoms forming an equilateral triangle base and the Carbon atom forming the top point of the pyramid. These pyramids are interlocked by bonding of the Iron and Carbon atoms in adjacent crystal cells into an intricate pattern of interlocking diamond shapes of Iron set into a rectangular array of Carbon atoms. This multi-facetted array of triangular shapes is extremely rigid, strong, and hard, but also extremely brittle. It has planes of weakness and once a Carbon/Iron or Carbon/Carbon bond breaks, it usually cannot be restored, allowing cementite to suffer catastrophic avalanch-type failure if the applied force ever exceeds the yield strength of the material anywhere within it. Cementite supplies the primary strength of steel and cast iron, while the ferrite supplies a cushioning and support role to keep the cementite from being directly impacted - much like even a single layer of paper can prevent brittle glass objects from breaking when they touch each other during shipping, while without the paper even a seemingly slight impact can cause the glass to shatter. Cementite is white in color. Brinell hardness of about 794 (an extrapolated value equal to 68 RC, the highest RC value).

Free Carbon

This is the only other form of Carbon in steel or cast iron and it usually is in the form of graphite, an extremely soft, weak, and slippery form of Carbon that is used as a lubricant and has some of these same properties in steel and cast iron when it forms. It can make cast iron and steel more brittle when compressed between irregularly shaped crystals, as in grey cast iron, but it can have the reverse effect if it forms between rounded crystals where it is free to move when put under pressure. For example, malleable cast iron (never used in armor) is made from hard white cast iron by heating the object to 927°C (1700.6°F) - well above the CHT but still solid - and holding it there for 50 hours until much of the Iron and Carbon has separated and then very slowly cooling it. It has many of the properties of low-Carbon steel (except for the steel's strength) even though it has a large amount of Carbon in its structure, almost all of it as large lumps ringed with thick ferrite shells sprinkled within a matrix of rounded pearlite crystals, while retaining the advantages of the low melting point of the original white cast iron when originally shaping the object by molding rather than by hammering, rolling, or forging. On the other hand, grey cast iron is made of very slowly cooled cast iron directly from the liquid state, so that the Carbon and Iron only partially mixes together as the metal solidifies and continues to cool very slowly through the austenite phase and past the CHT to the ferrite phase; most of the Carbon remains in the cracks between the ferrite crystals in strips and moderately large chunks or chips, where it renders the metal very brittle without increasing the hardness or strength of the metal very much, with only some pearlite being formed from the Carbon that did mix with the Iron as it cooled.

Pearlite

Crystal always containing 0.8% Carbon by weight - in the form of 88.1% ferrite and 11.9% cementite in an interleaved pattern similar to straight zebra stripes. It forms naturally in slowly cooling steel and cast iron. The ferrite and cementite complement one-another to make this a very good basis for making strong, yet ductile and tough, steel. Named after the way the tiny layers act as a diffraction grating to give a rainbow tint to the material under a microscope. Hardness increases as the original mixture's Carbon content or the cooling rate increases, as long as the transformation temperature does not fall below 538°C (1000.4°F), where another crystal bainite replaces it. As the 538°C boundary approaches, each pearlite crystal formed is harder and has thinner and more numerous stripes until at the boundary the metal seems to be a uniform grey color. The fixed 0.8% Carbon content is due to that being the Carbon content of austenite just above the CHT for the same reason that ledeburite has 4.27% Carbon: Above 0.8% Carbon, the excess Carbon will precipitate out of the austenite as cementite or free Carbon, though at a much slower rate than with a liquid/solid transformation, while below 0.8% Carbon, but above the 0.025% Carbon that ferrite can contain at the CHT, ferrite will slowly precipitate out until only 0.8%-Carbon austenite is left. Unless the cooling rate is so slow that ferrite and free Carbon form instead of cementite, pearlite will be formed directly from the austenite as the ferrite portion forms, coated with the extra ferrite, if under 0.8% Carbon, or extra cementite, if over 0.8%.

Ledeburite

Crystal made up of pearlite lumps imbedded in a matrix of cementite. Nearly white in color. Contains 4.27% Carbon by weight. Forms the major component of white cast iron and is created by very rapidly cooling Iron with over 2% Carbon from the liquid state using a chilling process of some sort to prevent the formation of grey cast iron, which is created directly from liquid Iron by very slow cooling by breaking up cementite into ferrite and free Carbon. Hard, but the existence of the relatively soft pearlite within it reduces the hardness compared to the cementite and martensite of high-Carbon steel that has been quenched in an optimum manner. Rather brittle, but less brittle than grey cast iron due to the extensive pearlite content. When the cooling rate is relatively slow, the pearlite lumps are rounded and look a lot like watermelon seeds, alternating with long zebra-stripes of pearlite, imbedded in the surrounding cementite matrix. When a very rapid chill is used, the stripes replace the seeds and the stripes get very thin and bunched into bundles that look like many black and white toothpicks of varying sizes packed together parallel to each other. The bundles from different crystals are jammed into each other at various angles, so that the white cementite is not obviously the surrounding medium (matrix) and any cementite and ferrite formed prior to the chill from the original liquid (when the Carbon content is not 4.27%) are bound tightly with the new cementite and ferrite formed inside the ledeburite to the point that they all seem to be the same. Makes up most the face layer of Grüson chilled cast iron armor, which probably had about 4% Carbon (typical). Brinell hardness can be from about 425-500, with the deep chilling needed for the Grüson armor requiring a rapid surface cooling that would tend to give the surface a higher hardness, estimated circa 475 Brinell.

Bainite

Similar to pearlite when viewed under a microscope, and having a similar range in Carbon content, though somewhat more random in its striping (more like a leopard than a zebra). Occurs when the cooling rate is fast enough so that the transformation from austenite occurs in the range 260-538°C (500-1000.4°F), with the lower the temperature, the more irregular, finer-grained, and harder it becomes. Near the 538°C boundary where pearlite stops forming, bainite is more brittle than pearlite without being much harder - this is called upper bainite due to the higher temperature of transformation - note that temper brittleness occurs in the 371°C (699.8°F) to 650°C (1202°F) range, which neatly boxes in upper bainite, indicating that they may be related. The 260°C boundary is where martensite forms instead of bainite. Just above this boundary, the form of bainite is termed lower bainite and it has many of the properties of martensite and is even used in martensite's place when brittleness is not a major criteria, using a hardening technique called austempering. Bainite has its cementite grains arranged in an elongated "fern-leaf" (radiating rib-like) pattern - with the lower the formation temperature, the smaller and finer the pattern - that pattern does not allow complete spheroidization, so tempering it does not work as well as with martensite. Bainite can also form when the quenching process is not carried out long enough to drop the temperature below the 260°C boundary to fully form martensite. Because upper bainite is relatively brittle without any advantage over pearlite, it is not desired in any kind of armor. The formation of upper bainite in the center of very thick plates of Japanese Vickers Hardened non-cemented face-hardened armor due to the use of the old pre-World War I (circa 1910) Vickers version of the Krupp cemented hardening process, which was never designed for such massive plates, caused them to split in two on impact, giving a perfect example of why this crystal structure was not desirable.

Retained Austenite

If the Iron above the CHT is suddenly cooled to 260°C (500°F) or less, its atoms cannot move prior to being frozen in place, so the austenite face-centered cubic structure remains. This also occurs at higher temperatures when the Carbon content of the metal is significant, but the time that it takes for the austenite and Carbon to change to the final lower-temperature form (pearlite or bainite or white martensite) varies enormously. Assuming the simplest case of 0.8% Carbon by weight, when the temperature is held barely below the CHT will it will take a long time (many hours) for austenite to change to ferrite, resulting in pearlite when it finally happens. When the temperature is dropped very rapidly to about 570°C (1058°F) and held there (the transformation temperature or "Hold Temperature"), it only takes about 0.8 second to begin to change to pearlite and 4.8 seconds for it to completely change. When the highest bainite temperature is reached as the Hold Temperature - 538°C (1000.4°F) - this is not changed by much, but as the Hold Temperature drops further, the time before transformation starts begins to increase again, but much more slowly so that it is only about 35 seconds at 260°C (500°F), the lowest bainite temperature, while the time to complete transformation to lower bainite at 260°C increases to almost 20 hours. When the Hold Temperature goes down to just below 260°C, a strange thing suddenly happens: The transformation from austenite stops happening and it will remain austenite indefinitely! As the Hold Temperature continues to go down, martensite begins to form instantly on reaching that temperature, with a fixed percentage of the austenite changing to white martensite at each Hold Temperature, no matter how long the temperature remains there. As the Hold Temperature continues to drop, the percentage of white martenite increases until all of the austenite is changed to white martensite instantly on reaching -73.3°C (-100°F). (The percentage of white martensite that is created is not a linear relation with decreasing Hold Temperature, but increases slowly near 260°C and -73.3°C and increases very rapidly in the middle, with 93.3°C (200°F) being the 50% transformation point.) The percentage of retained austenite at room temperature is about 20% - to eliminate this requires dropping the temperature of the object the rest of the way to -73.3°C for a short time to change it to white martensite or going back up to a near-CHT tempering temperature to change it to pearlite. Since austenite has a cell of about 3.57A (angstroms, each one-hundred-millionth (10^-8) of a cm) on a side (larger when heated to near-liquid temperature) and ferrite only has a cell size of 2.87A, the force on this structure as it tries to turn into ferrite is enormous, greatly increasing the brittleness of the metal. If the retained austenite is at room temperature after a quench to form white martensite, it also has the property that it will change spontaneously to white martensite, an even more brittle material, if the temperature drops (winter setting in or moving the object aroundin the ocean to near the North or South Pole), so the object is unstable from that angle also. The lower the Carbon content of the steel, the faster the initial temperature drop rate must be to form martensite and the more difficult this is to achieve, so the smaller the proportion of white martensite and the larger the proportion of retained austenite. The process of "tempering" has as one of its major goals the removal of this "retained" austenite so as to toughen and stabilize the metal. Note that some alloying elements lower the CHT to the point where austenite forms at room temperature regardless of the cooling rate, which obviously eliminates most heat treatments. This form of metallurgical property and timing modification by using alloying elements other than carbon is the reason for using them in the first place.

Martensite

Martensite has two forms: Fresh or white martensite, formed by the initial strong cooling to 260°C (500°F) or below from austenite, and tempered or yellow martensite, formed by a breakdown of white martensite into cementite and ferrite in a unique pattern. White martensite forms under the same conditions as retained austenite, with virtually none forming at the 260°C temperature (all retained austenite, instead) and a steady increase in percentage as the temperature of transformation drops until virtually all of the austenite turns into white martensite at -73.3°C (-100°F); this transformation is essentially instantaneous, unlike the transformation of austenite to pearlite or bainite, which may take some time if not assisted by various alloying elements (see retained austenite). White martensite is a face-centered tetragonal crystal, which has each cell consist of a rectangular prism (not a cube) 2.84A by 3A (for a 0.6% Carbon steel by weight; both axes get larger as the Carbon content of the crystal increases) - compared to austenite's usual cube of 3.57A (larger when Carbon is mixed in with it) and ferrite's 2.87A - made up of the eight original corner austenite Iron atoms forming a "cage" around a diamond shape made of the austenite's original six center-face Iron atoms now chemically bonded to the central Carbon atom that was in the austenite cell when cooling began (cells without the central Carbon atom also become white martensite but they are not chemically bonded, just locked into the shape by their chemically-bonded neighbors) - this diamond shape, longer than it is wide, is also one of the main components in cementite, so white martensite cells with Carbon in them can be viewed as cementite being formed inside of a ferrite crystal. The lower the Carbon content, the fewer chemically-bonded cells with Carbon in their centers exist and the more difficult it is to lock the white martensite shape into the crystals, so the faster the initial temperature fall must be to freeze in the austenite cell shape on which the white maternite cell shape is based. Conversely, increasing the Carbon content allows a slower quenching/chilling time to reach the white-martensite-forming temperature range desired and results in an increased hardness (more white martensite forms) for a given cooling rate. Various alloying elements, such as Chromium and Molybdenum, help to do this too, which is the only reason that high hardening levels used in deep-faced, KC-type face-hardened armors - which use rather large amounts of Chromium and, sometimes, Molybdenum - are practical with low-Carbon-content (necessary for adequate toughness) armor steels. White martensite is even more unstable than retained austenite and as brittle as glass and it will gradually break down into tempered martensite, though the rate of breakdown can be very slow - this may be a good trait in old Japanese swords, but not in production armor! By reheating the retained austenite/white martensite combination to near, but below, the CHT and holding it there for a time that depends on the temperature and the thickness of the object, both the retained austenite and the white martensite can be very rapidly changed to pearlite and tempered martensite, respectively, as well as allowing the metal to get the other benefits of tempering. Tempered martensite is much less brittle than white martensite and its crystal structure has oval lumps of cementite of many sizes formed into a series of rows (with very small cementite lumps randomly sprinkled around the rows) in a ferrite matrix (surrounding material), somewhat similar to pearlite with very fat, broken-up cementite layers - the higher the Carbon content, the higher the percentage of cementite and the harder the final product for a given cooling rate, though the hardness increase slows as the Carbon content approaches 0.8% and above, where the maximum possible hardness reaches an extrapolated 794 Brinell. This value (equalling 68 RC) can be compared to the absolute maximum Brinell Hardness Number that can be measured of 739 (65 RC) and the usual maximum value of 700 Brinell (62.8 RC) attainable in any repeatable production process and it is rarely attempted; the cemented layer's surface hardness in Krupp's cemented (KC a/A and n/A) and Italian Terni cemented armors (see WWI and post-1930) is, to my knowledge, the only time that even the hardest face-hardened armor has reached 700 Brinell and even here this was done only in the 1-1.5% Carbon by weight cemented layer by special processing and it was above the average of 670-680 Brinell (61-62 RC) maximum for most plates made by Krupp and well above the average of 650 Brinell (60 RC) maximum used by most other manufacturers of KC-type armor, with the lowest cemented surface layer hardness being in British World War II cemented armor and many World War I-era face-hardened armors, with 575-600 Brinell (RC 58) maximum. Increasing the amount of Carbon above 0.8% makes the steel easier to harden to a given level, but it also makes its much more difficult to toughen the metal to an acceptable level (more cementite), so armors never used over 0.55% Carbon - the average was 0.3-0.4% Carbon - except for the thin cemented surface layer of Harveyized mild- or nickel-steel and KC-type armors, which was immediately destroyed by the projectile impact, anyway. By using other alloying elements - Chromium and sometimes Molybdenum and, very rarely, Vanadium - to enhance the steel's hardenability (wringing out the maximum effect for a given amount of Carbon) and a lot of Nickel to make the steel tougher, rather high hardness was possible without increased brittleness due to using more Carbon.

Hardening cast iron and steel is done by rapidly cooling the object being made either in its entirety or on one surface of the object to harden the portion being so cooled due to the formation of higher hardness (and higher strength, though also higher brittleness) forms of the various crystal structures mentioned in I. Crystal Structures, above. Some of these heating and cooling techniques, such as tempering, can reduce hardness and increase toughness, so making steel is a sometimes complicated process of many steps.

Chilling

Cast iron and cast steel are hardened usually directly from liquid state by using a regular insulating mold for the portions of the object to be kept soft, so that these portions only gradually cool down to grey cast iron or pearlitic steel, while those portions to be hardened into white cast iron or martensitic steel are shaped by a mold made of a material that is highly conductive to heat and which is kept cool by having water or other material on its far side to carry off the heat - wrought iron or very low-Carbon steel is used for the "chill", as the portion of the mold that is conducting is called, in most cases due to its high melting point and its ability to retain its original shape until the object being cast has cooled down. Grüson chilled cast iron armor was the only major face-hardened armor made this way, but various small armor-steel fittings (cowls protecting sighting and range-finding gear sticking out of turrets, for example) have been made using chilled, face-hardened cast steel (though usually even these were kept homogeneous to reduce brittleness). The control of the temperature deep in the object being cast is not as good as with other cooling methods, so chilling is only employed when the details of the process are not critical and a relatively wide tolerance is allowed in the final results - the exact depth of face in the Grüson armor was not critical and matching an exact hardness pattern also was not necessary, since there is a rather wide range of values for the hardness and depth of face that give virtually identical results in face-hardened armor.

Quenching

Used on forged, rolled, and hammered steel to be hardened after previous mechanical and heat treatments have shaped the object to essentially its final form (only a small amount of machining for a tight edge fit with an adjacent plate in the case of armor and so forth will be done after hardening) and adjusted its crystal structure to that considered optimum (or at least acceptable) for the final product. Part or all of the object is heated above the CHT and then rapidly cooled by one or more of the following methods: Dipping the portion of the object to be hardened in hot or cold water; spraying that portion and, to prevent cracking due to thermal stress, usually the rest of the object with high-pressure water; dipping it into hot or cold oil; and dipping it into molten lead. These various methods control the final temperature (highest in lead and lowest in cold water) and the rate of heat removal (highest in cold water or, for large, thick objects, with the water spray - since steam formed can interrupt the cooling rate and the spray keeps the steam cleared away - and lowest with molten lead). For some objects, including some forms of face-hardened armor and most armor-piercing projectiles, several methods were used to reach the final hardness pattern and crystal structure.

Annealing

This is the opposite of chilling and quenching; here the object is softened to prevent cracking or to improve machinability by forming less cementite from the available Carbon. The thoroughness of this effort varies considerably. Normalizing is a form of mild annealing where the object is heated to a fixed temperature above the CHT and then allowed to cool down in open air by itself until it has reached a relatively low temperature (usually room temperature). This gets rid of many of the stress points in the metal after initial pouring and shaping and is usually the first step in the final manufacturing processes to turn the object into its final form - sometimes this step is repeated several times between various manufacturing processes to return the metal to a known baseline state. Full annealing is a deliberate, usually long-lasting, process of heating to very specific temperatures and then slow cooling in one or two ovens to specific final temperatures to ensure that the metal changes its structure at very specific temperatures, which controls crystal (grain) size and the softness, ductility, and toughness of the final product. This is the technique used on white cast iron to form malleable cast iron, for example, and it is an exacting process. Unlike quenching or chilling, these techniques even work with wrought iron, since stress points in the crystal structure can exist without anything to do with Carbon and thus annealing can reduce brittleness and make a more uniform final product.

Cementing

By either packing a steel plate's face tightly against bone charcoal (the original "Harveyizing" technique also used by most makers of versions of Krupp cemented-type armors) or by continually spraying the face with methane ("illuminating") gas (Krupp's version of this process also used by some other manufacturers), in either case in an air-tight oven raised to well above the CHT, the carbon would slowly soak into the austenite to a depth of about 1" (2.54cm) or slightly more over a period of about 2-3 weeks, raising the carbon content to about 1-1.5% by weight, which can easily be quench-hardened to the hardest kind of martensite afterward. Introduced in armor as Harveyized nickel-steel armor developed in 1890-91. Increased the surface hardness of any Iron or steel material, including Mild Steel, to 575-700 Brinell with no significant change to the rest of the plate after quenching the face (see Harveyized mild steel armor). Also known as case hardening or carburizing and widely used to get wear-resistant surfaces on items like ball bearings. Cementing is a very old method for hardening iron objects, originally using the technique of burying the object in the hot coals of the wood-burning furnace and leaving it there with the furnace kept at a high temperature. Krupp and some other early manufacturers tried to get a maximum surface hardness of circa 650-700 Brinell, but most manufacturers prior to 1930 were content to get a cemented layer of only 575-625 Brinell. After 1930, the average cemented layer hardness increased toward the Krupp value as more manufacturers became better at toughening the armor. However, after 1930 British World War II cemented armor was made on-purpose with a circa-600 Brinell cemented layer to minimize brittleness even in this sacrificial surface layer (it was always destroyed during an impact, whether or not it succeeded in damaging the projectile's nose). The success of this soft-cemented-layer British World War II cemented armor and Japanese World War II Vickers hardened non-cemented, face-hardened armor shows that the deep, decrementally-hardened KC-type armor face was much more important than the thin cemented layer when high-quality, hard-capped AP projectiles came into widespread use after World War I - Krupp, for one, retained this thin layer because of "tradition", not because it was still needed in its World War II KC n/A armor. However, thin high-strength steel armor used by armored cars and the like retained cementing as the primary face-hardening technique through the end of World War II as the entire face was essentially the thickness of the cemented layer by itself, anyway.

Decremental Hardening

This is a special form of quenching/chilling designed to get a deep, gradually-softening face on a face-hardened plate. Grüson Chilled Cast Iron armor formed its face using the chilling process, which was possible because of the very high Carbon content of the cast iron allowing rather rapid hardening. However, armor steels use rather low amounts of Carbon to prevent brittleness, so deep hardening is only possible by the use of alloying elements - primarily Chromium, though Molybdenum was used extensively after World War I in addition to Chromium - that slow down the transformation of austenite to ferrite, allowing martensite to form deeper in the plate where the cooling rate is slower, and that form additional carbides to increase the hardness by more efficiently using the existing Carbon. Nickel was also of use here, since it toughened steel considerably and allowed higher hardnesses to be used while keeping the toughness above the minimum required.

This process applied to steel was introduced by Krupp in 1894 as his famous Krupp Cemented face-hardened armor (later called Krupp cemented "old type" in Germany after World War I to separate it from the post-World War I improved KC "new type" ("KC n/A") developed by Krupp during the late 1920's and early 1930's) and in less than a decade had made all other forms of full-strength armor steel obsolete when used for the primary protection of warships and, later, armored land vehicles - including all previous homogeneous metal armors because his new Chromium-Nickel-Steel was harder and tougher and thus more resistant than the older Nickel-Steel. It was originally combined with the cementing process, but a few face-hardened armors dispensed with cementing and successfully (or not) employed decremental hardening by itself.

Except for a final, post-hardening temper (not always used in early KC-type armors) and minor machining, the decremental hardening process was the last heat treatment applied to a KC-type face-hardened Chromium-Nickel-Steel armor plate. The plate was completely heat treated for optimum crystal structure, mechanically worked (hammered, rolled, and forged), cemented (if used), and shaped to as close to its final form as possible, then laid flat and packed around the edges with an insulating layer of sand or loam, so only its face and back surfaces were exposed. Any portions of the face where holes were to be cut were covered with thick insulation (usually asbestos) to reduce both the rates of heating and of cooling and thus prevent hardening when quenched. All temperatures and times used were carefully regulated using data from previous tests and production runs. The plate was run into an oven and raised slowly to an even red hot temperature below the CHT, then the face surface only was evenly blasted by flaming jets to raise it to a much higher white hot temperature and the plate allowed to soak in this condition for a specified time, depending on the plate size and thickness. The CHT would gradually move into the plate in a flat front and when the timer indicated that it had reached the desired depth (which varied considerably between manufacturers and date made over a wide range), the plate would be removed from the oven and either both the face and back would be sprayed with high pressure water cold (original Krupp technique) or the plate would first undergo dipping of the face in water and/or oil (British Vickers KC-type armor manufactured prior to World War I, for example) prior to the final water quench.

The result was a "decrementally hardened" or "deep" face layer of circa 500 Brinell (535 Brinell is the hardest I know of, and not in a normal production plate) just behind the cemented layer (if used), dropping off gradually in hardness to the level of the unhardened back in one of several ways, depending on the final face and back temperatures, the heating time, and the plate's metallurgical makeup. The original KC a/A armor had the deep face layer's hardness drop off with increasing depth in either a straight line or a "ski-slope" (a rapid, ramp-like drop in the middle of the face layer, but slow near the surface and near the unhardened back, like a child's slide) to about 350 Brinell at about 20% into the plate from the face surface. At this point the drop in hardness would become much steeper in another ski-slope - the transition layer - until it merged with the back layer's circa 225 Brinell hardness at 33-35% of the plate from the surface of the face, being a constant hardness from there to the back surface of the plate. Except for the sudden drop in hardness at the back of the cemented layer (if used) of from 650-700 Brinell to the circa 500 Brinell level, in no place was there any sudden change in hardness, though there was the relatively sudden change in the rate that the hardness was dropping at the boundary of the deep face layer and the transition layer.

The cemented layer/deep face layer combined is also called the undrillable portion of the face, while the entire cemented layer, deep face layer, and transition layer combined is called the chill or, loosely, the face, though this can be confused with the more limited scope deep face layer part of the undrillable portion of the chill. The width of the undrillable chill portion, the width of the transition layer, the hardness level where the transition layer begins, and the average hardness of the back layer were all changed slightly or considerably by later adopters of this process, including, after World War I, by Krupp itself. KC n/A armor increased the back layer hardness to 240 Brinell (the maximum used by anyone); increased the depth of the chill to 41% (very exact value); and adjusted the hardness drop in the undrillable chill layer to exactly match the transition layer drop so that the chill went from about 500 Brinell just behind the cemented layer in a single straight line or gradually-flattening curve, making the point where the transition layer starts invisible (it should be when the hardness drops to somewhere around 350 Brinell, depending on whose definition of "undrillable" you use!). This armor was tempered and was much superior to KC a/A in every way.

In other face-hardened plates, the deep face layer hardness stays constant for some depth and then begins to decrease in a ski-slope (deep face layer/transition layer boundary again somewhat arbitrarily specified) or in a very sudden drop (essentially no transition layer at all). U.S. Navy Bethlehem thin chill Class "A" armor was unusual in that it had essentially no deep face layer, with the drop in hardness being so steep behind the cemented layer that the cemented layer itself became the entire face and only a narrow, very steep transition layer not much thicker than the cemented layer connecting the cemented layer with the back layer, while U.S. Navy Midvale non-cemented Class "A" armor had a extreme chill depth of over 80% of the plate. The depth of the chill (actually the thickness of the unhardened back layer as a percent of the total plate thickness) is important not only for damaging projectiles, but also because the hard chill always fails by breaking (brittle fracture) and this is a surface phenomenon, as opposed to ductile tearing, where the entire volume of armor is distorted and pushed aside by the projectile as it penetrates (see scaling). Due to the difficulty of precisely controlling temperature and due to the use of the circa-1"-thick cemented surface layer in most KC-type armors, the minimum plate thickness for the deep face process described above was usually circa 4" (102mm) or greater (6" (15.2cm) for Japanese World War I-era Vickers cemented armor, for example), though Krupp and Witkowitz originally made their KC armors down to 3.2" (8cm) up through the end of World War I - even they increased the minimum to 4" after World War I.

Historical Note

Decremental hardening is an old process. For example, it was used in Japanese swords and daggers for centuries: A low-carbon steel rectangular block was imbedded in the coals of a furnace, heated white hot, removed, folded in half, hammered back to its original shape, and put back into the furnace. This was done many times, creating thousands of thin parallel layers of low-Carbon steel alternating with high-Carbon steel from the soot adhering to the surface of the metal prior to folding. The block was finally hammered to its final, stretched shape with these layers parallel to its wide sides and polished, with the back edge of the gently-backward-curving sword thick and flat, its thickness kept constant from handle to tip (the end of the swords was beveled, since stabbing was not the purpose of the sword), and the sword body smoothly tapering cross-wise in a wedge shape to a single, razor-sharp edge where the many layers were crushed into a single mass of high-Carbon steel.

A thick, even layer of hard clay was coated over the back of the sword and the thick, upper portion of the sides, with this clay layer tapering in thickness to nothing just above the blade edge. The blade was evenly heated to "the color of the morning sun" (orange; perhaps 1000-1100°C (1742.4-1922.4°F)) and then suddenly quenched in cold water. The edge became solid white martensite and retained austenite and the cooling rate slowly decreased toward the thick back due to the insulating clay, forming less and less martensite mixed with the retained austenite, then bainite, then finally pearlite, with microscopically thin layers of low-Carbon steel separating the equally thin layers of high-Carbon steel (like pages in a book) parallel to the sword's side surface down the entire length of the sword, except near the sharp edge itself.

I do not know if a final temper was used after the hardening - perhaps the swords were allowed to gradually have their white martensite/retained austenite edge change to tempered martensite and ferrite due to air cooling over a long time like fine wine aging (hence the high regard for old blades)!

Tempering

This is the final, post-hardening, toughening process (related to annealing, but kept below the CHT at all times), where the internal stress points are allowed to smooth out and white martensite and retained austenite eliminated. It is also called drawing. Depending on the metal's composition, this process has the object heated to a specific temperature below the CHT and then cooled at a rather slow rate to another fixed, lower temperature; sometimes going up and down more than once. The most complete, highest-temperature form of tempering results in spheroidization, where the cementite crystals are rounded (into spheres, egg-shapes, or cylinders with rounded ends) and spaced apart in each ferrite crystal like seeds in a watermelon, giving the softest, toughest form of the metal for a given amount of cementite - tempered martensite is the best example of this effect. Tempering is supposed to toughen a steel object, but this is not as simple as it might seem: Chromium-Nickel-Steels have a temperature range of from 371°C (699.8°F) to 650°C (1202°F) where slow cooling during tempering of a quench-hardened steel, such as face-hardened Krupp cemented armor, results in a steep drop in toughness called temper brittleness. If the tempering treatment must go into this range, it is better to quench the plate for rapid cooling until the temperature is below the 371°C value before allowing slow cooling to continue. This is not a minor point. The pre-World War I U.S. Navy Midvale non-cemented Class "A" armor that was able to shatter the otherwise invulnerable (at under 15° obliquity against most armors made up through 1925, that is) U.S. Navy "Midvale Unbreakable" armor-piercing projectiles introduced from 1911 (8" (20.3cm)) to 1923 (16" (40.6cm)) at right-angles impact was found to only work due to the employment of a 343.3°C (650°F) final tempering treatment - tests using a 496.1°C (925°F) final temper caused the plates to act like pre-World War I Bethlehem Non-cemented Class "A" plates, which were very brittle and which were barely above the minimum acceptance level in quality (obviously, Midvale "lucked out" in using their tempering process, since temper brittleness was not understood until well after World War I, and just as obviously, Bethlehem did not have that luck). Also, tempering can result in loss of hardness, especially if it is kept at an elevated temperature for too long, since cementite is subject to decomposition into ferrite and free Carbon and, while very slow at below the CHT, this process is not infinitely slow until near room temperature (tempering in boiling water has been used at times - in Bethlehem Non-Cemented Class "A" armor, for example, in an unsuccessful attempt to increase its poor toughness - so the effects of even very modest heat treatments are not to be ignored). Tempering is the cause of the small drop in surface hardness in most face-hardened armors - the maximum hardness occurs a short distance behind the surface of the face - though Krupp and Terni made a major effort to prevent this and German Krupp KC a/A and KC n/A and Italian TC armors, uniquely, show no significant hardness drop at the surface (KC a/A was not tempered after hardening, but KC n/A and TC were, so this was not an accident). As with decremental hardening, tempering is an old process long used in sword making to reduce brittleness, which is where the original term "drawing" came from (e.g., drawing the brittleness from the metal).

Refrigeration

Cooling Iron materials below room temperature has a number of effects, some useful, though most causing problems. Cooling a white martensite/retained austenite hardened material shrinks the crystal cells and increases forces trying to convert the material's austenite to white martensite, so it sometimes is used to try to speed up this process in a particularly stubborn, slowly-changing quenched object where tempering the existing mixture is not desired. Even in a properly heat-treated material, strong cooling at or below the freezing point of water causes the crystals to shrink, splitting them apart and making the material more brittle as it can now more easily crack apart through failure between crystals, rather than through the interior of crystals. Cooling also makes the metal more rigid, which has the effect of increasing the yield strength without, unfortunately, increasing the tensile strength by much, if at all, so that the metal loses toughness (a sudden impact can reach the tensile strength limit and break the metal more easily if the gap between the yield strength, where the plate starts to give to reduce the instantaneous impact force, and the tensile strength narrows). If the toughness loss goes beyond the minimum necessary, the plate is said to have gone below its brittle-failure Critical Temperature (the lower this temperature is, the tougher the steel remains at any given temperature as it gets colder). Increasing the Carbon content makes it easier to harden steel, but it also makes it more subject to this form of brittle failure by raising this brittleness temperature, while Manganese also hardens steel, but actually lowers this temperature, which is a major reason that it is used in steel manufacture. Nickel lowers this temperature considerably; one of its many benefits. Therefore, the absolute minimum amount of Carbon should be used for any given level of hardness, with other alloying elements - preferably those that toughen the steel and/or lower the brittleness temperature - being used to make up for any loss in hardenability. Failure of a properly toughened Iron object at room temperature when suddenly folded is called a fiber failure because the material fails by shearing apart individual crystals and has the look of a ductile tear with rather smooth edges. If the object is cooled to successively lower temperatures and broken by folding, the failure zone begins to show jagged, sharp-edged, zig-zag breaks called grain due to brittle failure between crystals and eventually at the coldest temperatures, these make up all of the failures, with the metal being much easier to break. Good armor steel has to be cooled below about -50°C (-58°F) to begin to get grain to form, but poorer-quality (most older) Iron/steel needs only 0°C (32°F) to get some - sometimes a lot of - grain. (The TITANIC's hull steel suffered from this problem in the ice-cold North Atlantic, which is why the iceberg it hit was able to crack a narrow slot horizontally in the hull plates along so many spaces in the ship, which led to it sinking.)

Mechanical manipulation of Iron and steel, in addition to shaping it to the form needed for the final product, can modify its properties in a manner similar to, but usually less extreme than, heat treatments, due to the reshaping of the crystals in the metal by "brute force" and the localized heating and cooling of the metal on a microscopic level as it is squeezed and released, which is called work hardening - the breaking of a nail or tin can lid by bending it back and forth is caused to a large extent by the work hardening of the metal at the bending point that increases gradually at each bending cycle until the metal gets hard enough to act in a brittle manner and snap in two. Keeping the metal hot enough so that it never cools below the CHT during any mechanical treatments eliminates work hardening, though the other effects of crystal distortion and breakage remain.

Hammering

This is the oldest method of manufacturing soft Iron and steel, as applied by a blacksmith in making horseshoes, swords, and so forth, by hand. When the first large-scale wrought iron manufacturing plants were built in the early 19th Century they simply copied this technique using huge cast iron hammers powered by steam to lift them and gravity to drop them onto the Iron object being manufactured. It is still employed in manufacturing, but rarely for steel plates, since it is uneven, only affects a small part of the plate at each blow so that any large metal plate takes a long time to make, and can cause unwanted work hardening if the metal's temperature is not carefully controlled.

Forging

This is a direct offshoot of hammering where, instead of pounding the metal into shape, strong pressure is applied more slowly, though sometimes again and again, to force the hot metal to the desired shape, usually using a specially-formed tip to the press called a die. This reduces the effects of work hardening and allows shaping of objects in very complex ways. Since the advantage of gravity-induced velocity is lost, the steam-, hydraulically-, or, more recently, electrically-powered presses required to get enough pressure to bend and flatten large Iron or steel objects, such a thick armor plates, are enormous in size and somewhat expensive compared to any other method of mechanically working the metal, but the results are more controllable and usually superior. All U.S. manufacturers used forging for all heavy steel naval armor, with very good results.

Rolling

This is the most wide-spread method used for making Iron and steel plates, both construction and armor, since it gradually flattens the entire plate at one time, making the plate more even and much less time-consuming to manufacture. It has a few drawbacks, however. Any internal flaws in the metal, such as undissolved alloying element pieces or bubbles, are flattened out parallel to the plate face and thus act as laminations (gaps between layers in the plate) over a much wider area, where they can increase the chance of plate failure. Also, unless the plate is small enough to be able to fit under the rollers to be rolled sideways as well as up and down (depending on which end of the plate is defined as "up"), the crushing of the crystals will result in a wood-like grain in the metal that makes its strength, toughness, and so forth, different in the up/down direction than the left/right direction, which can also influence plate failure if a projectile hits an armor plate from a direction other than the most likely one designed against. A decided advantage of rolling is that even pressure over the entire plate can be used to apply work hardening to a plate by rolling it at a lower temperature, creating "cold rolled" steel which is hardened to a marked degree without having to use any other process that would increase the cost of the plate.

Iron makes up much of the earth's mass, composing most of the center 4,000-mile-wide (6,437 km) core of the earth, and being quite plentiful at the surface. It is normally a black metal about a third of the way through the Periodic Table of the Elements (symbol Fe) in atomic number (26), in atomic size, and in atomic weight (55.847 times normal no-neutron Hydrogen using the standard that the isotope Oxygen-16 weighs exactly 16.00). Iron weighs about 0.283 lb/cubic inch (40.8 lb/square foot for a 1"-thick plate) or 7.833 grams/cubic cm (78.33 kg/square meter for a 1 cm-thick plate), though this varies somewhat with Carbon content and alloying element content in steel, wrought iron, and cast iron used in construction and armor - grey cast iron with about 4% Carbon, by weight, only weighs about 0.255 lb/cubic inch since Carbon is so light that the 4% Carbon takes up much more volume than the same weight of Iron (some Carbon is in the cementite part of pearlite and the rest is free Carbon). It is the bottom of the element transmutation process in stars, requiring energy be added to either break it apart to form lighter elements or to fuse it with any other element to make heavier elements - it is thus not radioactive. It is rather chemically active, especially with Oxygen (in rust and in red blood cells where it transports Oxygen to the living cells in our bodies) and Carbon, and changes its crystal structure from ferrite to austenite with temperature while staying solid, which allows it to form cementite and martensite and thus become the basis of almost all modern manufacuring and construction using metal, including modern shipbuilding, making it the most important metal to human civilization. It is reasonably strong and tough by itself, but can be made much more so because it can form various alloys with other elements to modify its properties significantly, in addition to and/or in conjunction with Carbon. It is normally not poisonous to come into contact with (though eating too much in food or vitamins can be dangerous), allowing it to be widely used in complete safety (unlike some other poisonous metals like Lead, Mercury, and Beryllium). Most steels and cast irons are over 90% Iron, by weight, though some special alloys, such as maraging steels, have very large percentages of other alloying elements.

Carbon is the basic element making up living matter, including us, and, when burned in wood, coal, natural gas (methane), or oil, supplying most of the energy needed to keep our modern civilizations running. It is also used in making many things that modern (or in many cases any) human civilization needs, including our food, structures in the form of wood and plastic, and all animals and plants that keep earth a viable place to live. It is used as a catalyst in one of the main processes that fuse Hydrogen into Helium in the center of the Sun - the Solar Phoenix Reaction, which allows life to exist on Earth in the first place. In the form of carbon-dioxide, it is one of the major waste products of biological and human energy production and makes up a small fraction of the air we breath - carbon-dioxide is not poisonous, but can cause suffication if too much of it replaces the Oxygen in the air. It is very plentiful on Earth and comes in many forms: Graphite (black, flat, six-atom Carbon rings that are very soft, slide easily, and are useful as a lubricant and as the basis of many chemical compounds), diamond (eight-atom cubic cells that interlock to form a ferrite-like transparent Carbon crystal (but without the ninth atom in the center of each ferrite cell) that is the hardest known crystal on earth, with wide uses in industry and in jewelry), long chains (forming fibers and plastics and may other chemical compounds), and buckminsterfullerene (newly-discovered yellow 60-atom and larger Carbon molecules that form spheres and tubes and other shapes and which seem to be extremely useful in making many current and future previously-impossible-to-make materials with unusual properties). Carbon (symbol C) is very close to the beginning of the Periodic Table of the Elements with an atomic number of 6 and an atomic weight (the average of its three isotopes C₁₂, C₁₃, and C₁₄) of 12.01115 - C₁₄, which is mildly radioactive and which is being produced continously by cosmic rays in the upper atmosphere, is absorbed by living things while they are breathing and eating and is useful in dating once-living objects that are under 100,000 years old. Carbon is rather chemically active, but it normally does not react easily with Iron unless made to by rapid cooling or due to the chemical activity of some other alloying element added to the metal. Carbon in the form of graphite, as it is found in the free Carbon in Iron materials, has a density of 0.0812 lb/cubic inch (2.249 grams/cubic cm), so the percentage of Carbon given by weight in steel and cast iron can represent a larger volume of the final metal, even if the Carbon atoms are smaller. Carbon can exist in a produced Iron object as free Carbon in the form of graphite in steel and cast iron, it can chemically combine with the Iron to form cementite and martensite under some conditions, or it can chemically combine with some other alloying element added to the metal, such a Chromium, to form hard carbides of that element under some conditions, allowing steel and cast iron to be hardened considerably and allowing Iron to get most of its beneficial properties. The history of Iron manufacture is also a history of the use of Carbon in Iron for the most part. Only wrought iron does not use much Carbon (under 0.08% Carbon by weight, the usual minimum for steel).

Silicon is the next most widely used element with Iron after Carbon, found in almost all Iron materials used as armor or construction material. It is very plentiful, making up most of quartz beach sand, it is used by some microscopic plants and animals to build their protective shells, and it is used by people to make such things as glass and, more recently, micro-electronic circuits. It is relatively chemically inert, though it will chemically combine with Oxygen to form a very inert thin protective film that prevents any further reactions, and usually it is a good heat and electric insulator. Silicon (symbol Si) is nearly halfway between Carbon and Iron in the Periodic Table of the Elements, with an atomic number of 14 and an atomic weight of 28.086. Silicon weighs about 0.09 lb/cubic inch (2.5 grams/cubic cm), markedly increasing the volume of an Iron material that uses a lot of Silicon more than the percentage by weight would indicate. Silicon was used in the original form of construction Iron, known as wrought iron - as opposed to small things like swords, shields, body armor, horseshoes, and the like made previously of Iron and steel by hand - that is a very-low-carbon product to prevent brittleness (handling steel was - and to a marked degree still is - an art and what worked in a blacksmith shop by hand did not necessarily work with a multi-ton mass of Iron under a steam hammer) and used Silicon, from clean sand, in large amounts (up to 7% by weight, though mostly 3-4%) to assist in melting and softening the hot Iron and to prevent rust in the finished product. Very little of the Silicon entered the ferrite crystals, with most of it, in the form of a thin translucent slag or "stringers," coating the ferrite crystals at the object's surface in a rust-proof wrapping. Inhibiting rust in otherwise very rust-prone Iron was one of the most attractive features of using Silicon (it does not completely protect Iron from some kinds of corrosion, but normal water-caused rust is stopped almost completely - the very first all-Iron armored warship, the British HMS WARRIOR, built in 1860, is still afloat and was recently turned into a British museum because its wrought iron hull remained intact after well over 100 years of contiuous immersion in salt water!). The Silicon also acts as a soldering flux to allow large masses of Iron to be smelted separately and hammered together while red hot into one homogeneous mass, which was necessary since low-Carbon Iron was almost impossible to melt with the furnaces of the time (prior to 1890) and they could only manufacture rather small amounts of Iron at a given time, requiring a large object, such as a thick armor plate, to be made out of several smaller Iron ingots. Silicon in high percentages causes graphite to separate from Iron, allowing even Iron that has a small amount of Carbon to be used as wrought iron, and it removes Oxygen from Iron that has already begun to rust, which greatly reduces the need for quality control - this skill was rather lacking when wrought iron was first introduced in construction and armor! Silicon is usually used in much lower percentages in steel armor and construction material, usually close to 0.25%+/-0.1% by weight in World War I-era armors and down to 0.05-0.1% in many World War II-era armors, though it may be used in the original smelting process in higher percentages to scour out excess Oxygen before being removed itself prior to the final steel ingot manufacture. It causes a modest increase in the hardness of steel (and slightly hardens wrought iron, too) and resists losing hardness during post-quench tempering of hardened steels, including face-hardened armor. Usually used with the hardener Manganese, which it complements. By proper heat treatment, mechanical working, maximum elimination of impurities, and thorough mixing of all additives, Silicon and Manganese have become a major replacement for Nickel in making moderately hard and tough high-strength construction steels, including such top-of-the-line High-Tensile Steels as British Colville post-World War I "D"-Steel, which was only slightly more brittle than Nickel-Steel and just as strong, even being used as light armor when Nickel shortages or tight cost restraints required it. These two elements in combination are also used in all armor steels as the base-line hardening agents that Nickel, Chromium, and Molybdenum improve upon.

Manganese is a rather common element used extensively in steel manufacture. It is only mildly chemically active, but it has a great affinity for Sulfur, which it combines readily with, and it thus can be used to eliminate Sulfur from steel or to reduce the effects of any remaining Sulfur by chemically combining with it, which is important since Sulfur softens steel and is not desired in any construction or armor steel that I am familiar with, though it is used in many steels needing to be soft for ease of machining, as on a lathe (Phosphorus has a similar effect on increasing machineability and it can harden steel, but it raises the temperature where brittle failure sets in, so it is also reduced to a minimum in naval construction and armor steels, allowing Manganese to lower this temperature, as mentioned previously). It also acts to increase the hardenability of low-Carbon steel much better than Silicon does, but does not help keep the hardened metal hard during tempering as Silicon does, which is one of the major reasons that it and Silicon are used together as a team. Usually used in amounts of about 0.4% by weight in armor steels containing other hardeners such as Chromium, it is used in amounts of 0.6-1.1% (depending on plate thickness) in Mild/Medium Steels used for construction and up to 1.3% in high-strength construction steels, such as HTS and "D"-Steel. Manganese (symbol Mn) is just below Iron in the Periodic Table of the Elements, with an atomic number of 25 and an atomic weight of 54.938. It has a density of 0.267 lb/cubic inch (7.396 grams/cubic cm).

This is the first successful toughening alloy element used in steel, being used in small amounts in the first High-Tensile Steels, such as British HT and Krupp "Low-%" Nickel-Steel, and in the 3-4% by weight range in virtually all full-strength Nickel-Steel and Chromium-Nickel-Steel armors introduced from 1889 on (except for the Harveyized mild steel armor). It can also harden steel somewhat by itself, but it has a strong effect of increasing the effect of Chromium (see below) in hardening steel, both due to a multiplying effect of combining multiple alloys in a steel, especially complementary alloys like Nickel and Chromium, and due to the toughening of the steel by the Nickel allowing stronger, deeper hardening processes to be employed than possible with Chromium by itself. A large part of Nickel's toughening ability is that its atoms are close enough to Iron to allow it to mix into the Iron crystals very thoroughly, but different enough to impede a crack trying to pass across these atoms, acting as a crystal defect - much like a speed-bump in a parking lot or piece of cloth in a zipper. Nickel also very strongly lowers the brittleness temperature of any steel containing it. It is used in amounts of 2-3.5% in the new, very high strength ship construction steels such as U.S. Navy HY-80 through HY-180, used primarily in modern, deep-diving submarine hulls. Nickel (symbol Ni) is two numbers above Iron in the Periodic Table of the elements, with an atomic number of 28 and an atomic weight of 58.71. It has a density of 0.313 lb/cubic inch (8.665 grams/cubic cm).

First used to harden steel armor-piercing gun projectiles circa 1890, it was introduced in 1894 as a hardening alloy in armor by Krupp and was used in all subsequently developed full-strength armor steels for ships and armored land vehicles. Chromium, in conjunction with Nickel, finally allowed steel armor to be deep-hardened like Grüson chilled cast iron armor, making possible Krupp cemented (KC) face-hardened armors and the derivative non-cemented face-hardened armors without the need of cast iron's high Carbon content, which promoted brittleness. About 1.5-3% Chromium by weight was and is used in these armors. Small amounts (under 1%) were also used in some of the early high-tensile steels, especially Krupp "Low-%" nickel-steel, but most of these steels used no Chromium, relying on other alloying elements - primarily Silicon and Manganese - to achieve their modest hardening requirements. Chromium forms its own carbides, more efficiently using the available Carbon; increases the ductility of steel somewhat; greatly slows down the rate of transformation of austenite to ferrite to allow slower cooling to achieve high hardening deep inside a thick armor plate (see Decremental Hardening); and provides some corrosion resistance to the metal (though this last is not very strong in the rather low percentages of Chromium used in armor steels). Modern U.S. Navy HY-80 through HY-180 naval construction steels all use about 1-1.8% Chromium for hardening. Chromium is relatively expensive. Chromium (symbol Cr) is two numbers below Iron in the Periodic Table of the elements, with an atomic number of 24 and an atomic weight of 51.996. Chromium's density is 0.248 lb/cubic inch (6.856 grams/cubic cm).

A hardening alloy similar to Chromium, but stronger in its hardening power; so much so that it was restricted to 0.4% or less in all armors that used it (Krupp World War II-era armors had a sliding percentage that decreased the amount of Molybdenum as its armor plates got thicker). It was not used in any construction steels. Originally introduced by the French in 1912, when Krupp accused the French of "cheating" in a comparative armor trial that the French won that year by using a small amount of Molybdenum in their Chromium-Nickel-Steel armor! Used extensively in post-World War I armor, though only U.S. manufacturers Bethlehem and Midvale used this alloying element in their armor and restricted it to post-1930 U.S. Navy Class "B" homogeneous armor under 7" (17.78cm) made by Bethlehem (0.3-0.4% Molybdenum) or under 15" (38.1cm) made by Midvale (0.2-0.3%). Has another effect that promoted its use, in that it increases the toughness of Iron when white and red hot, allowing faster, more extreme mechanical working on the plates without fear of causing cracking; time is money! Reduced temper brittleness. Modern U.S. Navy HY-80 through HY-180 naval construction steels all use about 0.2-0.6% Molybdenum in addition to Chromium for hardening, but this was done to compensate for reducing Carbon to only 0.18-0.2%, the same Carbon content as in the Bethlehem armor just mentioned, which is the lowest Carbon content ever used in a Chromium-Nickel-Steel armor. This reduction in Carbon content in the HY steels made welding easier and more reliable - welding steel, especially armor steel, was a problem not completely solved until after World War II - and these plates were used in submarine pressure hulls, where any failure of a weld is the beginning of catastrophe. The loss of the submarine USS THRESHER is presumed to be due to a failed weld during a deep dive. The loss of the battleship KM BISMARCK was also due to this welding problem, since the entire stern almost fell off, jamming its rudder, when hit by a small British aircraft torpedo that broke the excessively-brittle aft strength welds. Molybdenum (symbol Mo) is well above Iron in the Periodic Table of the elements, with an atomic number of 42 and an atomic weight of 95.94. Molybdenum's density is 0.368 lb/cubic inch (10.185 grams/cubic cm).

Copper has some of the toughening properties of Nickel, but not as great and only one nation, Japan, ever used Copper in its armor steels to any great extent. Japan had a shortage of Nickel and found that it could substitute up to 0.15% Copper for an equal percentage of Nickel in its armor steels introduced during the 1930's. During the 1930's, it also found that higher percentages of Copper - up to 0.85% - could be used to replace that much Nickel in homogeneous armors under 3" (7.62cm) in thickness, due to the higher intrinsic toughness of such thin plates (see copper non-cemented (CNC) and "Wotan Starrheit" (Wsh) armors) - with further development (CNC1 and CNC2 armors) resulting in a modest reduction in Chromium, too, by replacing about 0.25% of it with an equal amount of Molybdenum, and in increasing the maximum thickness of CNC armor to 3.21" (8.15cm). Since much more thin armor was used than thick armor, this greatly reduced the drain on Japan's Nickel supply and a more modest reduction in its need for Chromium. Small amounts of Copper are allowed in modern high-strength naval construction steels, but it is not a major contributor to these materials' properties. Copper (symbol Cu) is three numbers above Iron in the Periodic Table of the elements, with an atomic number of 29 and an atomic weight of 63.54. Copper's density is 0.322 lb/cubic inch (8.915 grams/cubic cm).

Vanadium is a hardening alloy element in steel that is much stronger in its effects than either Chromium or Molybdenum. Resists "metal fatigue" from repeated loading below the nominal yield strength, which can cause the metal to gradually stretch out of shape ("creep"), so it is widely used in springs in small amounts. It is also used in small amounts in some very-high-strength steels, but not in any modern U.S. Navy HY-type construction steels. Only naval armor use, to my knowledge, was 0.1-0.14% by weight in post-1930 U.S. Navy Class "B" homogeneous armor plates under 7" thick made by Bethlehem, which also were the only U.S. Navy armor plates that used Molybdenum in amounts similar to British and German armors (0.3-0.4%) and which contained the lowest amount of Carbon, 0.18-0.2%, of any Chromium-Nickel-Steel naval armor. Very expensive. Vanadium (symbol V) is three numbers below Iron in the Periodic Table of the elements, with an atomic number of 23 and an atomic weight of 50.942. Vanadium's density is 0.198 lb/cubic inch (5.487 grams/cubic cm).

Usage

Laboratory specimens only.

Pure ferrite at room temperature. Pure Iron rusts easily, so it is a poor material to use in any normal environment.

Average Quality (estimates)

Year	Rating
1855	0.6 (French)
	0.55 (British and others)
1870	0.6 (all)

Usage

All naval armor and ship construction.

First ferrous construction and naval armor material. Also formed the back layer of British-developed compound face-hardened armor.

Average Quality (estimates)

Year	Rating
1876	0.7
1890	0.75
Post-World War I	0.8 (when hit by projectiles up to 8", dropping off slowly and steadily when hit by projectiles above this size at a rate between German Wsh and U.S. STS, depending on material's Percent Elongation)

Usage

Ship construction and some early armor.

Wide range in quality. Older steels very brittle, but eventually became the high-quality material used today for most ship construction. First armor was 22" (55.88cm) vertical plates for 1876 Italian battleships manufactured by French Schneider & Co. of Gavre, which literally fell apart when hit by large projectiles, but which could shatter any of the standard chilled cast iron projectiles (German Grüson type and British Palliser type) then in use, preventing them from penetrating this armor even if the armor did break to pieces in the process. Until 1890, only Schneider & Co. had the skill to make thick steel armor plates, though a gradual improvement in expertise allowed steel to be used more and more in less demanding roles. Percent Elongation varies from a low value equal to German Wsh to a high value equal to U.S. STS, so the scaling results must be decided proportionately for each material separately.

Average Quality (estimates)

Year	Rating
1895	0.8
Post-World War I	0.85 (when hit by projectiles up to 8", dropping off slowly and steadily when hit by projectiles above this size at a rate equal to German Ww)

Usage

Ship construction, light armor, "Protective decks," and anti-torpedo bulkheads.

Later versions used more alloying elements, but only a little Nickel was used in original "recipe." Usually used in multi-layer laminates of 1-2" (2.54-5.08cm) per layer. Has a Percent Elongation equal to German Ww with similar scaling results.

Schiffbaustahl III was the equivalent of British HT high-strength shipbuilding steel. Used in Germany as HT steel was used in Britain, except where Krupp "Low-%" Nickel-Steel was used, instead. German shipbuilders tended to use much less HT-grade steel (Schiffbaustahl III) than British shipbuilders, using regular Mild/Medium Steels (Schiffbaustahl I or II) as much as possible. "Ste. 42" and "Ste. 52" were higher-quality steels than Schiffbaustahl II and III, which they largely replaced, though not quite as strong in tensile tests, being among the strongest of the Mild/Medium Steel types, though their improved properties in all other ways more than made up for the small loss in ultimate tensile strength. These steels have Percent Elongations between German Wh and Wsh with proportionately similar scaling results.

Small percentage of Chromium and Nickel, but otherwise like Krupp "high-%" nickel-steel armor. Used in Germany for primary "Protective" decks and anti-torpedo bulkheads just as HT steel was used for this plating in Britain, with Schiffbaustahl I, II, or III used elsewhere where British shipbuilders would use HT steel. Have a Percent Elongation between German Wh and Ww with proportionately similar scaling results.

Average Quality

Rating
0.9 (when hit by projectiles up to 8", dropping off slowly and steadily when hit by projectiles above this size at a rate equal to German Ww)

Usage

Ship construction, light armor up to 2" (5.08cm), and anti-torpedo bulkheads.

Developed by British Colville Co. in 1920's as "DuCol" (British Navy "D" or "D.1" grade) low-alloy, top-grade construction steel. Widely used in British, Japanese, and Italian post-World War I warships. Germany and the U.S. did not use this material through the end of World War II, preferring full armor-grade materials (STS or "Wotan" steels) when the usual mild/medium steels or HTS were not sufficient or ballistic protection was needed. After World War II, these steels became the basis of the highest grades of the commercial shipbuilding steels. (Many World War II Russian tanks were made of this steel type due to lack of sufficient Chromium and Nickel supplies.) Has a Percent Elongation equal to German Ww with similar scaling results.

Average Quality

Year	Rating
1889 (original mild steel w/3-4% nickel)	0.76 (from DeMarre Ni-Steel AP Formula) (against projectiles up to 8", dropping off slowly and steadily when hit by projectiles above this size at a rate between German Wh & Ww)
By 1900	0.9 (against projectiles up to 8", dropping off slowly and steadily when hit by projectiles above this size at a rate between German Wh & Ww)

Usage

All armor and armor construction support.

Up to 7% Nickel by weight (usually circa 3%) added to otherwise standard mild steel to drastically improve toughness under projectile impact. Even after being superseded by the later Chromium-Nickel-Steel armors (Krupp "high-%" nickel-steel and later types), it was used as the underlying support layer for many armored areas - U.S. World War I battleship deck armor using STS originally had a bottom layer of Nickel-Steel under the one- or two-layer STS plating - and for armor-attachment bolts, nuts, and rivets to the present day. Introduction of Nickel-Steel armor in 1889 by French Schneider & Co. was the reason British-developed compound armor (a hardened Mild Steel face fused to a thick wrought iron back plate) became completely obsolete. Also, it was used as the basis of U.S.-developed Harveyized nickel-steel face-hardened armor introduced in 1891. Has Percent Elongation between German Wh and Ww with proportionately similar scaling results. Greatly improved during 1890's by improved tempering processes allowing harder steel.

Average Quality

Rating
0.95 (when hit by projectiles up to 8", dropping off slowly and steadily when hit by projectiles above this size at a rate between German Wh and Ww)

Usage

Turret and conning-tower roofs and vertical light armor up to 3.15" (8cm).

Also known as "Krupp Soft" or, in Krupp's own nomenclature, "Qualitat 420 Stahl." It was the same high-quality steel used for Krupp's KC a/A face-hardened armor, but without the face hardening applied. Used for full ballistic protection when highly oblique impacts were expected or plate thickness was below the minimum possible for reliable KC armor manufacture (circa 3.15" (8cm) in the World War I German Navy, but later raised to 4.1" (10.5cm) by Krupp or higher by other nations) - "low-%" nickel-steel was considered good enough for decks because several laminated and spaced decks and bulkheads would have to be pierced to reach the ship's "vitals" (this logic was refuted later when long-range "plunging" fire by improved projectiles with reliable delay-action fuzes became the norm after World War I). This material formed the basis of all subsequent highest-grade armor and maximum-strength construction steels for ships and armored land vehicles. Maximum thickness of this kind of armor used for heavy vertical plating was restricted due to an erroneous idea that ductile, homogeneous armor steel was always inferior to face-hardened forms of the same steel at near-right-angles impact conditions. Testing by the U.S. Navy in 1921 of thick STS and face-hardened plates showed that the face-hardened armor only had an advantage when the damage that it caused the projectile was above a certain level (shatter of uncapped projectiles was always well above this level); if not, the hard, brittle face either did nothing to help or, in many cases, actually made the armor inferior to its unhardened form. As projectiles improved, the conditions where face hardening was the preferred solution became more and more limited. In fact, the U.S. Navy retained homogeneous armor for its heaviest turret faces during World War II when they discovered that it was better than any face-hardened armor against their own virtually indestructible armor-piercing projectiles when hit nearly square-on, as would be the case for a turret pointed directly at an enemy warship (face hardening was retained for thinner cruiser turret faces because the hard face caused less of a problem in these lower thicknesses and because uncapped projectiles were more likely to be used against the ship). This original form of Chromium-Nickel-Steel used 1.75-2% by weight of Chromium, 3-3.5% Nickel, and 0.35-0.4% Carbon. Has a Percent Elongation between Ww and Wh with proportionately similar scaling results.

Average Quality

Rating
0.97 (estimate when hit by projectiles up to 8", dropping off slowly and steadily when hit by projectiles above this size)

Usage

Vertical main turret forward side armor in new post-World War I "Panzerschiffe" ("Armored Ships") of the DEUTSCHLAND Class (also called 'Pocket Battleships').

Used new-composition Krupp Steel Type PP755. Improved "high-%" nickel-steel with a large perentage (0.4-0.5% by weight) of Molybdenum added, the amount of Chromium increased slightly, the amount of Phosphorus and Sulfur allowed reduced slightly, the amount of Silicon used increased considerably, and the amount of Nickel used decreased to only half what was used previously. This material also formed the metal used to make the original form of post-World War I "Krupp Cemented New Type" (KC n/A) used for the face plates of those same turrets. This composition was found to be brittle in thick plates and was not repeated in the later version of KC n/A (which was never used in its non-face-hardened form), though the thinnest grades of the improved thick-plate KC n/A material are similar to this original version. Since "Wotan Härte" (Wh) homogeneous armor was also used in these ships for all other full-strength homogeneous anti-shell and splinter-resistant armor (decks, belt, turret roofs, turret aft side and rear armor, light gun shields, etc.), the use in this portion of the turret, where hits at very high obliquity would be expected at all striking velocities (range is not as much of a factor as with horizontal deck armor) and where the armor is somewhat thicker than the Wh material used elsewhere in those ships, seems to indicate that perhaps Krupp was having trouble making even moderately thick plates of Wh at the time (circa 1930) so it was simpler to use the homogeneous form of the current version of KC n/A armor for these somewhat thicker plates (the other armor on the Panzerschiffe was thinner (turret roofs and decks, for example) and/or subject to less highly oblique impacts (belt armor, as an example of the latter).

"Wotan Härte" (Wh)

"Hardened 'Wotan' Armor Steel"

Average Quality

Rating
1.00 (when hit by projectiles up to 8", dropping off slowly and steadily when hit by projectiles above this size)

Usage

Almost all horizontal, sloped, and vertical armor up to 4.72" (12cm) for decks and 8.66" (22cm) for smaller areas to protect against direct hits for German post-World War I armored warships.

Improved "high-%" nickel-steel with Molybdenum added. Equal to the best non-German homogeneous armor in steel quality, but the very low Percent Elongation seems to result in a rather large scaling effect when hit by projectiles over 8" (20.3 cm), according to German "G.KDos. 100" 20.3cm, 28 cm, and 38 cm Wh armor penetration tables - verified by post-World War II tests of Wh plates up to 17.32" (44 cm) using U.S. Navy 8", 12", and 14" AP projectiles at the U.S. Naval Proving Ground (now Naval Surface Warfare Center, Dahlgren Division), Dahlgren, Virginia.

It was not used for forward side armor of turrets in the 'Pocket Battleships', where a homogeneous form - "Krupp Non-Cemented" (KNC) armor - of the steel used in the original version of KC n/A armor was used instead, though Wh was used as the homogeneous armor elsewhere in these ships.

"Wotan Weich" (Ww)

"Soft 'Wotan' Armor Steel"

Average Quality

Rating
0.95 (when hit by projectiles up to 8", dropping off slowly and steadily when hit by projectiles above this size, but at a slower rate than with Wh)

Usage

Anti-torpedo bulkheads and some light-to-medium armor against fragments and blast.

Form of Krupp "Wotan" armor material that was especially softened in an attempt to get the enhanced strength of Wh without the reduced ductility of Wh, since maximum ductility is needed to prevent an anti-torpedo bulkhead from snapping at its joints (welds, bolt-holes, rivet-holes, the edges of bracing ribs, etc.) under the shock of a torpedo warhead or mine blast. Actual tests and wartime experience indicated that there was no significant difference between Wh and Ww when hit by underwater blast shock, possibly due to "work hardening" under the concussion stress negating the initial softness of the metal or from the fact that materials under high-speed shock-type loads do not act the same as they do when slowly stressed, as was the case of the standard metallurgical testing done at the time - Izod and Charpy toughness tests do not simulate shock waves! Also, German (and most foreign) welding practice prior to and during most of World War II was subject to "Hydrogen embrittlement" (Hydrogen nuclei in the welding rod stripped of their single electrons and migrating into cracks where they prevent bending and, thus, make the metal brittle), which compromised welds so much that the plate material used was of much less importance than it would otherwise have been. However, the low Percent Elongation would seem to result in a large scaling effect when hit by projectiles over 8" (20.3 cm) in diameter, though much less than with Wh armor.

"Wotan Starrheit" (Wsh)

"Extra-Hard 'Wotan' Armor Steel"

Average Quality

Rating
1.10 (when hit by projectiles up to 8", dropping off slowly and steadily when hit by projectiles above this size, but at a higher rate than with Wh)

Usage

Armor for use against lead machine gun bullets and fragmentation up to 1.97" (5cm).

Special extra-hard form of "Wotan" armor for use on the spherical anti-aircraft directors used by World War II German heavy warships and in similar lightly-protected areas. Similar in principal to the extremely hard British and American "Homogeneous Hard" aircraft armor of thicknesses up to 0.5" (1.27cm) used to protect fighter and bomber crews, but not as extreme due to its greater thickness. Manufacture was possible because thin metal plates can be hardened (and thus strengthened) to a high level while retaining enough toughness. Similar to tank armor, which is made of higher hardness to protect against close-range, high-velocity projectile impacts, which is also true here since aircraft strafing will be at close range and projectile fragments are moving at a high velocity near the point where their filler explodes. Very low Percent Elongation should result in larger scaling effects than with Wh.

Average Quality

Rating
0.95 (when hit by projectiles up to 8", dropping off slowly and steadily when hit by projectiles above this size at a rate equal to German Ww)

Usage

Turret and conning tower roofs and vertical armor up to 4" (10.2cm).

British form of Krupp "high-%" nickel-steel armor and used in a similar manner, though the minimum thickness of British Krupp cemented (KC) face-hardened armor was higher to make it easier to get a reliable product (face thickness was somewhat variable and the thinner the plate, the larger the effects became of any small variations). For most purposes, laminated and spaced HT steel was used instead since World War I-era projectiles usually could not penetrate very deeply into a target due to over-sensitive explosive fillers (picric acid or trinitrophenol - British "Lyddite," French "Melanite," Japanese "Shimose," etc. - being the most common of cause of this problem), non-delay fuzes, and rather poor penetration ability through thick armor, especially at oblique impact. Also formed the basis of Japanese and Italian armors of similar type. Has Percent Elongation equal to German Ww with, I assume, similar scaling results.

Average Quality

Year	Rating
Original	1.00
Mid-World War II	0.9-0.95 (most thin plates)

Usage

Turret and conning tower roofs, armored decks, vertical armor under 4" (10.2cm) where "D"-steel was not used instead.

British high-Molybdenum-content naval armor directly replacing previous "KNC" (0.4% Molybdenum was used, the highest amount used by anyone and close to the highest that can be used in armor without degrading the plate's quality). Same composition as the standard British World War II face-hardened cemented armor without the hard face. "D"-steel was used extensively in plates up to 2" (5.08cm) instead of NCA to reduce costs. Normally equal to any foreign armor of its type, but quality control seems to have been lax for the thinner grades during World War II, possibly due to war-time supply problems and rushed manufacture.

Average Quality

Rating
1.00 (estimate, when hit by projectiles up to 8", dropping off slowly and steadily when hit by projectiles above this size at a rate similar to German Wsh)

Usage

Turret and conning tower roofs, armored decks, and vertical armor 1.97" (5cm) to 2.76" (7cm) where British-type "D"-steel or the heavier AOD armor was not used instead.

Italian armor replacing World War I British Armstrong KNC armor previously used by Italy for light armor from 1.97" (5cm) through 2.76" (7cm) in thickness. Used about 0.15% Molybdenum and 0.06% Vanadium - otherwise of more-or-less standard World War II Ni-Cr-Steel composition. "D"-steel, called by the Italians "Acciaio Elevato Resistenza," was used extensively in plates under 1.97" (5cm) thick instead of POV to reduce costs and AOD armor was used for thicker plates. Data from one 1.97" plate and one 2.76" (7cm) plate for battleship DORIA. I assume that this armor was equal to all foreign armors of this type, but I only have the test data (taken from a British Report on Italian World War II armor) that the plates had no through cracks when hit at 60-65 degrees obliquity at about 80% of the striking velocity for complete penetration by 253.5-lb uncapped Italian 8" AP projectiles, according to my M79APCLC program against a standard quality plate (the Percent Elongation has no effect in these tests). Has Percent Elongation similar to German Wsh with similar scaling results.

Average Quality

Rating
1.00 (estimate, when hit by projectiles up to 8", dropping off slowly and steadily when hit by projectiles above this size at a rate similar to German Wsh)

Usage

Turret and conning tower roofs, armored decks, vertical armor 2.78" (71mm) through 3.94" (10cm) where British-type "D"-steel or PO-with-Vanadium light armor was not used instead.

Italian heavy armor, also called "Piastro Omogenee" ("Homogeneous Plate"), replacing WWI British Armstrong KNC armor previously used by Italy. British-type "D"-steel, called by the Italians "Acciaio Elevato Resistenza," was used extensively in plates under 1.97" (5cm) thick and POV was used for plates 1.97" through 2.76" (7cm) instead of AOD to reduce costs. AOD used roughly a very high 0.47% Molybdenum, a small 0.03% Vanadium (but more than most foreign armors did), and a rather high 0.38% Carbon content, but was otherwise similar to most other World War II Ni-Cr-Steel armors. The data here is from a single 7.84" (20cm) thick AOD plate from a lot for battleship VITTORIO VENETO's main armament turrets, probably the roof armor, since the plate was flat. The data indicates a plate considerably harder than most non-Italian heavy homogeneous armor; which is significantly harder than I previously thought - similar to average World War II U.S. Army rolled homogeneous tank armor or German Wsh light armor. I assume that this armor was equal to all foreign armors of this type, taking into account the resistance reduction against large-caliber shells due to the low Percent Elongation, but I have only the following tests (taken from a British Report on Italian World War II armor): When hit at 65 degrees obliquity by a 12.6" (32cm) uncapped Italian AP projectile of 941.4 lb (427 kg) weight and 2053.1 ft/sec (625.8 m/sec) striking velocity (well below the penetration velocity calculated by M79APCLC for a standard plate), only a small dent was made; and when hit by a 10" (25.4cm) uncapped Italian AP projectile of 476.2 lb (216 kg) at normal (0 degrees) obliquity and 1221.1 ft/sec (372.2 m/sec) striking velocity, a small hole was made in the plate back, but the projectile broke up and bounced off, the latter impact being about 90% of the complete penetration velocity according to my M79APCLC program assuming a standard quality 225-Brinell plate adjusted for the significant resistance reductions due to the low Percent Elongation with these larger projectiles. Thus, the plate was at least a quality of 0.9, but could have been up to 1.00 and still fit the test results.

Average Quality

Year	Rating
1910	0.95
1930	1.00 (the "Standard" Armor)
1941-45	0.95 (thin (2" (5.08cm) or less) "MOD" STS plates used only for blast and fragment protection)

Usage

Vertical hull armor under 4" (10.2cm) before 1930 and under 5" (12.7cm) thereafter; armored decks; 12-2" (30.5-5.08cm) tapered lower armor belts; and in blast- & fragment-resistant hull, decks, and vertical bulkheads.

Also known as Protective Deck Plate. U.S. Navy Bureau of Construction and Repair (later Bureau of Ships) form of Krupp "high-%" nickel-steel used on all portions of a warship needing homogeneous direct impact protection armor, except gun mounts and conning towers, where the very similar U.S. Navy Bureau of Ordnance Class "B" armor was used. Somewhat more ductile than the average for any similar armor, even Krupp's post-World War I Ww armor. Prior to 1930, armored decks using STS were of 2- or 3-ply laminated construction with STS laid above a layer of nickel-steel armor. After 1930, STS was lavishly used for amidships hull construction above the waterline and as the foundation-layer for heavy armor plate of any kind, including more STS. Originally introduced by the Carnegie Steel Corporation (the largest of the three major naval armor manufacturers in the U.S. through the end of World War II, when it was called the Carnegie-Illinois Steel Corporation) for thinner armor, tests in 1921 of 13" (33cm) STS plates showed that homogeneous armor was superior to heavy face-hardened (U.S. Class "A") armor when projectiles that neither armor could damage appreciably were employed (the Midvale Co., who also made high-quality armor-piercing (AP) projectiles, had just introduced its new 8-16" (20.3-40.64cm) "Midvale Unbreakable" soft-capped AP projectiles, which were virtually impervious to damage by most World War I face-hardened armors at right-angles impacts, of which the 12" (30.5cm) Mark 15 Mod 6 was used here). Equal to the best foreign armors of its type. Note that Molybdenum was never used in this armor, to my knowledge, unlike most contemporary World War II foreign manufacturers of similar Chromium-Nickel-Steel armor. Only U.S. naval armor-grade material not made by either Bethlehem or Midvale in any quantity, to my knowledge.

Average Quality

Rating
0.95 (when hit by projectiles up to 8" in diameter, dropping off slowly and steadily when hit by projectiles above this size at a rate equal to German Ww)

Usage

Turret and conning tower roofs; gun mount, director, and conning tower armor under 4" (10.2cm).

Armor manufactured by Carnegie Steel Corp., Bethlehem Steel Corp., and the Midvale Co. was mixed together in a "crazy-quilt" arrangement, so each plate could be from any manufacturer, but homogeneous armor tended to be similar in any case (this was not true for Class "A" armor prior to 1930!). Rather high hardness. Equal to all foreign homogeneous armors at the time, but has a Percent Elongation equal to German Ww with similar scaling results.

Average Quality

Rating
1.00 (the "Standard" Homogeneous Armor)

Usage

Turret roofs; gun mount and director armor under 5" (12.7cm); conning towers; turret face (port) armor 16" (40.64cm) thick and up.

Armor still manufactured by the same three steel makers (Carnegie was now Carnegie-Illinois Steel Corp.), but now all armor of a given type was made by the same manufacturer on a given single ship, with no more mix-and-match. Significantly improved steel, but only a slight improvement in ballistic protection, since this form of armor had always had plenty of toughness (Class "A" armor benefited much more from these improvements). The use of homogeneous Class "B" armor in turret faces (either as a single thick plate or as a not-quite-so-thick plate laminated to a 2-2.5" (5.08-6.35cm) Class "B" support plate) was an extension of the results of the 1921 tests of 13" (33cm) STS, where the even more indestructible World War II U.S. armor-piercing projectiles made the situation even worse for Class "A" armor compared to Class "B" armor. (It turned out that most foreign projectiles were not nearly as good as U.S. designs at oblique impact, but this was not known at the time and might not have made enough of a difference in any event to alter the turret face plate material.) The thinner face plates used on U.S. cruiser turrets had less of a resistance difference between Class "A" and "B" against the smaller projectiles used against them and much more chance of being hit by uncapped projectiles that might be able to penetrate if the hard face was not there to shatter them, so Class "A" armor was retained for turret faces when U.S. Navy cruisers switched to Class "A" armor for new ships circa 1937. Also, Class "A" armor was retained on the sides and rear of the all turrets and on the cylindrical barbettes under the turrets, where the armor was somewhat thinner - but still thicker than in most non-US Navy World War II battleships - and was much more likely to be hit at a medium-to-high obliquity (30° and up) where the face could destroy even a high-quality projectile, though at over about 55° obliquity a ductile Class "B" armor plate would again be desirable because a ricocheting projectile might punch out a very dangerous, cork-like armor plug from a Class "A" plate, which rarely happens with good Class "B" armor, especially at high obliquity. Post-1930 U.S. warship armored conning towers used Class "B" armor so that they could be welded, riveted, and bolted into the surrounding superstructure to save weight - the rigid face of face-hardened armor could not be welded or drilled without weakening it or allowing it to tear itself free upon any substantial impact shock. As a result, U.S. Class "B" armor on new battleships was the thickest homogeneous Krupp-type armor ever used. The Midvale Company used 0.2-0.3% by weight Molybdenum in this armor under 15" (38.1cm) thick and Bethlehem Steel Corp. used 0.18-0.2% Carbon (the lowest amount of Carbon in any Krupp-type armor, to my knowledge), 0.3-0.4% Molybdenum, and 0.1-0.14% Vanadium (the sole use of this element in any U.S. Krupp-type armor; to my knowledge, only Terni of Italy also used it extensively, but only in its AOD and POV homogeneous armors to any significant amount) in plates under 7&qout; (17.78cm) thick.

Average Quality

Rating
0.95 (when hit by projectiles up to 8", dropping off slowly and steadily when hit by projectiles above this size at a rate between German Wh and Ww)

Usage

Turret and conning tower roofs, vertical gun mount and conning tower armor under 12" (30.5cm) except for thin plates where one of the CNC armors was usually used, armored decks other than where MNC was used, 8-3" (20.3-7.62cm) tapered lower belt armor on IJN YAMATO Class, cruiser/aircraft-carrier vertical armor except where CNC or "D"-steel was used for light armor or fragmentation protection.

High-Carbon (0.5-0.55%) steel replacing both British Vickers KNC homogeneous armor and KC face-hardened armor (called Vickers cemented in the Japanese Navy) - in the latter case its face-hardened form was called Vickers hardened (VH). The high Carbon content was the highest used by a successful homogeneous armor and equaled the highest used for any other mostly-successful face-hardened armor - pre-World War I U.S. Midvale non-cemented face-hardened armor. This high Carbon content allowed easier heat treatments to obtain a given level of hardness, but caused the plates to be somewhat brittle, though no worse than the World War I-era armor that they replaced. This armor was kept at about the same quality level as its British-developed predecessor, making it slightly inferior to most World War II foreign homogeneous armors. Used up to 0.15% Copper to replace an equal amount of Nickel due to shortages of Nickel in Japan. Has a Percent Elongation between German Wh and Ww, with proportionately similar scaling results.

Average Quality

Rating
0.97 (when hit by projectiles up to 8", dropping off slowly and steadily when hit by projectiles above this size at a rate between German Ww and U.S. STS)

Usage

Used exclusively for the main deck armor of the WWII IJN YAMATO Class battleships.

Not to be confused with U.S. pre-WWI Midvale non-cemented face-hardened armor.

Replaced NVNC only in this single purpose; NVNC was used everywhere else that had heavy homogeneous armor in the IJN YAMATO Class. Only slightly better than NVNC, it is not obvious whether this armor, which used 0.3-0.42% Molybdenum and a more conventional 0.35-0.42% Carbon, was a copy of British World War II NCA or German Krupp Wh armors - one source says that it was based on German armor - or a completely original Japanese product. Production plates were mostly in the thickness range of 7.87-9.06" (20-23cm), though a huge 14.96" (38 cm) thick MNC grating plate with many cylindrical holes was placed over the openings of the funnel uptakes in the armored deck to keep out projectiles; from U.S. tests, this plate would only be about 40% as resistant as a solid plate, so the effective thickness of it is only about 6" (15.2cm) of solid MNC armor (a large, inclined, several-deck-high, 1.97" (5cm) CNC plate was wrapped around most of the lower portion of the funnel above the grating, so there was less likelihood of a direct bomb hit and the CNC plate would add some small additional protection to the grating against projectiles hitting at high obliquity). As with NVNC and VH, 0.15% Copper was substituted for that amount of the strategic material Nickel as a conservation measure. Has a slightly low Percent Elongation, between German Ww and U.S. STS, with proportionately lower scaling results.

Average Quality

Rating
0.95 (when hit by projectiles up to 8", dropping off slowly and steadily when hit by projectiles above this size at a rate equal to German Ww)

Usage

All places where a full-armor-grade material was required in plates up to 3" (7.62cm) thick (original CNC type) or 3.21" (8.15cm) (later CNC1 and CNC2 types), if British-type "D"-steel was not acceptable.

Nickel was in relatively short supply in Japan and a major attempt was made to reduce the amount of it in all high-grade armor. A small amount of Copper could be substituted for Nickel in the heavier plates - up to 0.15% of Nickel could be so replaced, but no more since the loss in toughness was unacceptable. However, for plates below 3" thick, it was found that Copper could replace more Nickel, up to 0.85%, in an NVNC-type plate, renamed CNC, without lowering toughness below the minimum specification level because thin plates had more inherent toughness due to various scaling effects (German Wsh and British/U.S. "Homogeneous Hard" aircraft armor are examples of this). In the later CNC1 and CNC2 grades introduced in World War II, up to 0.25% Molybdenum was added and a similar percentage of Chromium deleted, allowing plates up to 3.21" to be used with the reduced Nickel content of CNC. CNC development was thus a moderately successful effort, as much more thin armor was used (thick armor was usually restricted to battleships). Until World War II, when combined U.S./British efforts resulted in breakthroughs in low-alloy construction steels (rarely applied to armor, though), this was the only successful attempt at strategic material conservation. Has a Percent Elongation the same as German Ww with similar scaling results.

Armor Quality

Q	QD	BLT	TC	CW	SS
0.7	Q	See discussion.	Y	Y	0

Usage

Vertical and sloped side armor for dome-shaped heavy gun turrets used in land and coast defense forts.

The armor was cast and hardened simultaneously in crescent-shaped wedges, widest and thickest in the middle where they were vertical and narrowest and thinnest at the top and bottom edges where they curved back to about 60-70° from the vertical. The wedges were soldered together with zinc-based low-temperature solder to form wedding-band-shaped rings with a curved profile that had a smaller diameter at the top and bottom edges than at the side midpoint. The upper edge was grooved to seat a shallow, dome-shaped, flush-fitting wrought iron protective roof of at least 3" (7.62cm) thickness and the lower edge was sunk into a flattened-cone-shaped concrete glacis completely surrounding the turret. Two adjacent oval gun ports were formed into the heaviest wedges for the turrets, which could be mechanically rotated to train in any direction. They used guns from 5.9" (15cm) to over 11" (28cm). The hardened face (chill) was roughly 33-55% of the plate thickness: 33% in 33.07" (84cm) plates - the thickest solid armor ever used, to my knowledge - for the gun port plates of large coast defense forts and increased linearly (estimate) to 55% for plates 15.75" (40cm) thick, being a constant 55% for thinner plates down to the thinnest plates of this type made, 7.87" (20cm) - the side and rear armor of most turrets was half the gun port plate thickness and most land forts with the smaller guns used a 15.75" gun port thickness.

This face was formed by using the chilling process directly from the liquid metal to hardened white cast iron, while the rest of the plate was formed using the standard sand mold to form slow-cooled grey cast iron, with a gradual change from one to the other. The chill depths are estimated from

1. A description of a land fort plate made by a visitor to the Grüson factory.
2. The fact that this form of hardening does not have the ability to control the rate of cooling with as much precision as heating a solid plate in a furnace and then quenching it.
3. Trying to cool the chill too fast would result in the brittle cast iron cracking or even breaking apart due to thermal stresses.

Grüson armor was of the highest quality even though cast iron was normally quite brittle and it could shatter even the best steel projectiles of the period without any significant damage, even when hit in the same spot many times. Though not used aboard ship (no flat plates were possible), this armor later formed the basis of all Krupp cemented (KC) armors after Herr Krupp bought Herr Grüson's factory to learn his secrets.

Armor Quality

Q	QD	BLT	TC	CW	SS
0.75	0.6	70 (average)	N	N	0

Usage

Heavy vertical armor.

British answer to French Schneider & Co. solid homogeneous mild steel armor that had been introduced in 1876. At the time only the French company could make any Mild Steel armor at all - 22" (55.88cm) plates were made in 1876 - and even they had severe breakage and brittle behavior problems that were only accepted because the steel armor could stop projectiles that wrought iron could not. The British, who could not allow the French to eclipse them and who in 1876 just had their vaunted new "100-Ton Gun" defeated by the 22" French armor (the plates disintegrated in the process, but the gun could not pierce the French Mild Steel), decided to get the advantages of thick Mild Steel without as many of the brittleness problems. They made a regular wrought iron plate and a thinner 1%-Carbon (by weight) Mild Steel plate, glued them together with liquid steel, heated them red-hot and rolled them into a single plate with 67-75% of the plate's thickness being the wrought iron back, and then heated the entire plate above the austenite-forming temperature and quenched it cold. The Mild Steel face hardened at its surface to an estimated 400 Brinell (probably dropping down to circa 200 Brinell at its back where it joined the wrought iron plate), while the wrought iron plate was not changed by this heat treatment. Later Compound plates were fused together more tightly by using the wrought iron plate as the bottom of the mold for pouring the steel face, so that they fused together from the start. The Compound plate's hard steel surface caused much more damage to any of the projectiles then used than homogeneous Mild Steel armor did and this compensated for the weaker wrought iron and brittle steel face, as well as the fact that plain Mild Steel has never been very tough under impact shock (it is primarily a construction steel, not armor) and such all-steel plates of the period tended to break apart and not always stop the better steel projectiles. However, this complete reliance on poor projectile quality eventually killed Compound armor when Schneider & Co. introduced nickel-steel armor in 1889 and tests by the U.S. Navy at Annapolis, Maryland, in 1890 showed the absolute superiority of the new extra-tough French Nickel-Steel armor and of improved, tougher Mild Steel armor against the high-quality steel projectiles used in the test. Compound armor was made under license by all nations except France at the time, since making it was easier than solid Mild Steel and, until Nickel-Steel and good steel projectiles arrived, just about as good. Compound armor cannot shatter any steel projectiles, capped or not, though other forms of damage can still occur. Only naval armor made from two separate, but permanently bonded, plates (though some World War II light face-hardened armor for armored cars and so forth was bonded from two plates: steel-faced steel or steel-faced aluminum).

Armor Quality

Q	QD	BLT	TC	CW	SS
0.766 x QMOD	0.86 x Q	100 x 1.25"/actual thickness inches	Y if BLT > 75 (>5" plate); N otherwise	N	0

Usage

Vertical armor 6" (15.2cm) and thicker.

Mr. H.A. Harvey of New Jersey, U.S.A., was the first to develop an all-steel, single-plate, face-hardened armor, originally made from homogeneous Nickel-Steel armor (see Haveryized nickel-steel for details, including the unusual effects of projectile damage against this kind of thin-faced plate), but later also successfully applied to less expensive, though weaker, Mild Steel armor by some manufacturers during the 1890's. Both forms of armor were the first unqualified successes of face-hardened armor in warships, since British compound armor never completely proved itself superior to French solid homogeneous mild steel armor. The fixed total average face thickness of circa 1.25" (3.18 cm) means a variable face thickness percentage, but the minimum plate thickness of this type ever used was about 6", to my knowledge, though test plates down to 3" were manufactured (similar to the thin cemented tank and armored car armor used after WWI for some vehicle armor up to circa 2-2.5" (5.08-6.35cm) thick), so the face was always rather thin by later KC armor standards. The effects of this type of face-hardening was to make plates that were of decreased resistance as plate thickness increased against any size projectile, whether they damaged the shell or not (though of course at low obliquity they had better resistance if the shell was broken up or, better yet, had its nose shattered on impact).

Armor Quality

Q	QD	BLT	TC	CW	SS
0.791 x QMOD	0.86 x Q	100 x 1.25"/actual thickness inches	Y if BLT > 75 (>5" plate); N otherwise	N	0

Usage

Vertical armor 6" (15.2cm) and thicker.

Prior to applying his Harveyizing (cementing) process to mild steel plates, Mr. H.A. Harvey of New Jersey, U.S.A., applied it to the superior nickel-steel armor just introduced in 1889 by Schneider & Co. of France. In fact, the first plate Harvey used for his perfected process was a 10.6" (27cm) Schneider & Co. Nickel-Steel plate "Harveyized" at the U.S. Navy's Washington Navy Yard in 1890. The superior performance of Grüson chilled cast iron armor was due to its very hard face shattering the projectile on its surface, prior to the projectile doing any significant damage to the plate. Mr. Harvey reasoned that steel was stronger than cast iron so that the deep face was not as important as making the surface as hard as possible, even if the hard region was very thin - once the projectile nose shattered, penetration ability dropped significantly, sometimes considerably. (He was not quite correct in this, as later, deep-faced Krupp cemented (KC) armor demonstrated.)

To accomplish this, Harvey adopted the old "cementation" process followed by hardening heat treatment ending in a water quench to form a super-hard, very-high-Carbon surface layer about 1-1.5" (2.54-3.81cm) - averaging 1.25" (3.18cm), which is the value I use in my FACEHARD computer program - thick after first annealing and mechanically treating the plate to optimize its properties and shape it. The much lower Carbon content in the rest of the plate and restricting the heating and quenching to just the surface of the plate face resulted in only a slight increase in the plate's general hardness and brittleness. It was obvious to him that the best steel available, French Nickel-Steel, would give the best results when cemented using his new process. This proved to be true and Harveyized Nickel-Steel armor became the armor of choice for vertical protection by all nations during most of the 1890's, being only gradually replaced by the superior, but much more expensive, KC armor in the late 1890's and early 1900's. However, it was the introduction of soft-capped armor-piercing projectiles during this time frame that was the major deciding factor, since KC was significantly superior against them because its deep face could cause considerable penetration-reducing damage to the projectile in addition to shatter - when shatter occurred, it gave KC-type face-hardened armor types an effective bonus of, on the average, a 30%-or-so increase in effective plate thickness against a right-angles impact - so KC armor could reduce penetration whether or not shatter occurred well beyond any merely Harveyized armor type. The fixed total average face thickness of circa 1.25" means a variable face thickness percentage, but the minimum plate thickness of this type ever used was about 6", to my knowledge, though test plates down to 3" were manufactured (similar to the thin cemented tank and armored car armor used after WWI for some vehicle armor up to circa 2-2.5" (5.08-6.35cm) thick), so the face was always rather thin by later KC armor standards.

The effects of this type of face-hardening was to make plates that were of decreased resistance as plate thickness increased against any size projectile, whether they damaged the shell or not (though of course at low obliquity they had better resistance if the shell was broken up or, better yet, had its nose shattered on impact), but for the most part still have better resistance than a regular Nickel-Steel plate under the same low-obliquity (near right angles) conditions. The changing face thickness percentage with plate thickness modifies the projectile-size-caused scaling effects, but this has very little effect when plates are over about 6" thick (scaling is pretty small by then, anyway) and rather few plates thinner than that were used, to my knowledge, so this is not an important factor in most cases.

For Harvey plates over 8" thick, the shatter of the projectile nose on the hard plate, if it occurs, does not give the plate its usual advantage of circa 30% increased plate effective thickness at right-angles impact found with the majority of thick-faced face-hardened armors (compound and KC types) against most projectiles. What happens is merely that the Holing Limit (where a hole is punched in the plate, but the projectile body, other than some pieces, cannot go through it), which is a specified velocity percentage lower than the Navy Ballistic Limit (complete penetration of at least 80% of the projectile, if in pieces, or 100% - other than the windscreen and AP cap - if intact), is raised to equal the unshattered NBL value, just as is more-or-less true with a homogeneous plate (which essentially it is, other than that thin cemented surface layer) at right angles. The shattered NBL is then raised by a rather small percentage above this new HL.

Since a shattered shell is usually in several or many pieces, increasing the striking velocity from the HL to the NBL only gradually increases the number of projectile pieces that go through the plate to the 80% value, which has rather little added effect when perhaps 40-50% of the shell's pieces were punching through at the HL, on top of the huge chunks of armor punched out due to the large, irregular hole in the plate (usually 50% or so larger than a smooth unshattered projectile hole at low obliquity). Thus, the HL is the major damage-causing ballistic limit to the space immediately behind the armor hit when shatter occurs, not the NBL.

For Harvey plates under 8" thick when shatter occurs, the HL begins to increase above the unshattered NBL value used with the thicker plates as plate thickness goes down until at 3" thickness it is about as wide a gap between the shattered and unshattered HL values as with KC armor, which it is approximating with the 1.25" cemented face on a 3" total plate thickness. Thin Harveyized plate is not inferior to thin KC armor, at least when compared to the original Krupp KC a/A armor introduced in 1894.

An interesting point of law occurred in the U.S. concerning this armor: In 1892 Mr. Harvey formed the Harvey Steel Company to manufacture his patented (U.S. Patent Number 460,262) armor and signed a contract with the U.S. Navy for manufacture of his new armor by his company or, under license with royalties to be paid, by other companies for the U.S. Navy - he also licensed the manufacture by several foreign firms. Several U.S. warships were constructed using his armor during the 1890's, but the U.S. Navy refused to pay him his royalties for the armor because the improved manufacturing techniques used differed slightly from those given in his patent. He took the U.S. Government to court and on January 16, 1905, the U.S. Supreme Court unanimously stated in "U.S. VERSUS HARVEY STEEL CO, 196 U.S. 310 (1905)", in effect, that Harvey Armor was Harvey Armor, regardless of nit-picking details, and awarded Mr. Harvey his royalties.

Armor Quality

Q	QD	BLT	TC	CW	SS
0.828	Q	65	N	N	0

Usage

Vertical armor 3.2" (8cm) and up for Krupp and Witkowitz; 4" (10.2cm) elsewhere.

Renamed "KC a/A" ("KC Old Type") by the German Navy after KC n/A was introduced, this armor was developed by Friedrich Krupp of Essen, Germany, using Herr Grüson's process for making Grüson chilled cast iron armor. It was one of the first non-French major strides in steel-making and it became the basis for virtually all later full-strength steel face-hardened or homogeneous armors on warships and, later, on tanks. It combined the Harvey "cementing" process for a thin, super-hard face to shatter projectile noses with a deep Grüson-Chilled-Cast-Iron-type face to smash the rest of the projectile afterwards (the cemented layer was destroyed along with the projectile's nose and did not help in any other projectile damage). When added to the improved steel quality due to the combination of Chromium and Nickel working together to toughen and evenly harden the plate, this deep-face bonus ranged from 10-20% of effective plate thickness increase beyond that of a Harveyized Nickel-Steel plate if the projectile shattered to an even better bonus of 13-26% if it did not shatter (i.e., capped projectiles when the AP cap worked) - shatter gave a 30% plate thickness increase bonus at right-angles impact to thick-faced face-hardened armors when it occurred, but thin-faced Harveyized armor caused much less projectile damage of any kind than deep-faced KC armor, especially when shatter did not occur. Krupp changed the cementing process to use a continuous blast of methane ("illuminating") gas against the plate face in an air-tight oven, but few other manufacturers ever changed from the original Harvey method.

As with thick Grüson armor, a back of 65-67% of the plate's thickness was used, made here of unhardened, extremely tough steel, which acted as a buttress and shock absorber to keep the plate from breaking during the period when it was demolishing the projectile. The combination of Nickel and Chromium alloy had a multiplicative effect that was better at toughening and hardening the plate than either element alone (see "high-%" nickel-steel), so that a higher hardness could be tolerated and the Chromium allowed hardening entirely through the plate to any level from 190 Brinell (minimum possible with this metal type) to about 535 Brinell (highest possible with the Carbon content used) and to various values in-between, which was not possible with Nickel by itself. The drop in hardness from the face surface to the boundary with the soft back had to be carefully controlled to keep the face from breaking (spalling) off of the back at the boundary (a major shortcoming of compound armor due to the abrupt change in hardness at the steel/wrought iron boundary) - loss of the cemented layer had little effect on plate resistance, since it had done its job (or failed) before the rest of the plate began to resist the projectile, but loss of an appreciable part of the deep face radically reduced the plate's resistance (this is the major cause of the improvements in projectile penetration when hard armor-piercing caps replaced soft caps gradually after 1911, since the hard caps could gouge a pit in the plate face as they were destroyed, rather than just flattening out like a soft clay ring on the plate surface).

By simply heating the face surface evenly to well above the austenite-forming temperature and keeping the back surface below it, carefully controlling both surface temperatures, and then timing how long the plate was allowed to "soak" in this condition, the critical austenite-forming temperature point would slowly move into the plate and the plate's inner temperature at any point could be controlled, allowing a deep decrementally hardened chill of practically any desired depth, as well as many possible hardness patterns in the hard face and transition layers (the latter, if it exists, usually softens much more rapidly than the hard face layer) to allow "tuning" the armor to what the manufacturer thought was optimum (rightly or wrongly). If the surface was first cemented, as in most of these face-hardened armors, the result was a thin super-hard (575-715 Brinell maximum) Harvey-like layer, backed by a 475-535-Brinell-or-so maximum hard face layer that softened as one went deeper into the plate in one of many possible ways (different manufacturers changed this considerably over the years), ultimately reaching the 190-240 Brinell back layer hardness in one or more steps or gradual drops (the last one being the transition layer). KC a/A itself had a total chill depth of 33-35% of the plate (as in the thickest Grüson Chilled Cast Iron armor), of which the first circa 20% was "undrillable" chill (including the cemented layer), with the maximum circa 650-700 Brinell hardness at the face surface and with constant drop in hardness with depth behind the cemented layer from circa 500 Brinell to circa 350 Brinell, and then a transition layer of 13-15% of the plate that smoothly connected the back of the high-hardness portion of the chill to the ductile back in a ski-slope (no abrupt change anywhere).

KC was more expensive than Harveyized armor due to the use of Chromium in its alloy and due to the necessity of introducing and perfecting the deep-face hardening process that KC armor required (special handling equipment and furnaces had to be used that were not necessary for Harveyized plates). Krupp did a much better job than most other manufacturers in toughening the back layer of its plates, as is obvious in the very good ductility when tested by the British after World War I in numerous firing trials against the surrendered battleship BADEN, but due to excessive conservatism, Krupp never changed from testing its plates with uncapped projectiles (no capped projectiles existed when KC a/A was originally developed in 1894), so Krupp never understood the need to also toughen the face of the plate to delay face damage as long as possible, which was necessary to get the best results against capped projectiles, which did not shatter instantly on the surface as uncapped projectiles did - the improved Austro-Hungarian Witkowitz KC armor shows what Krupp could have accomplished if proper testing against the actual threat (capped projectiles) had been done systematically and KC a/A armor modified to optimize it for those projectiles. The post-World War I statements that British armor was better than German armor was true for KC a/A, though not true for any other kind of German armor. The drastic improvements that led to World War II KC n/A show that Krupp had no technical reason for this inferiority and could improve its armor when it was forced to admit inferiority. Krupp and Witkowitz made KC down to 3.15", (8cm) but most other manufacturers needed more slack, so they raised the minimum to 4" (10.2cm) or greater. After World War I, Krupp also realized that improved homogeneous armor was better than KC in such low thicknesses due to its greater toughness (see "Wotan Starrheit" (Wsh)), so Krupp used a 3.94" (10cm) minimum for its new KC n/A armor.

Armor Quality

Q	QD	BLT	TC	CW	SS
0.90	Q	59	N	N	0

Usage

Vertical 5.91" (15cm) turret face on new post-World War I "Panzershiffe" ("Armored Ships") of the DEUTSCHLAND Class.

Used new-composition Krupp Steel Type PP755. Improved form of "Krupp cemented" (KC) face-hardened armor for plates from 3.94" (10cm) to 5.91" (15cm) thick used exclusively by the Pocket Battleships with a large perentage (0.4-0.5% by weight) of Molybdenum added, the amount of Chromium increased slightly, the amount of Phosphorus and Sulfur allowed reduced slightly, the amount of Silicon used increased considerably, and the amount of Nickel used decreased to only half what was used previously. This material also formed the homogeneous metal used to make the forward side plates of the main armament turrets of these ships, but was used nowhere else. This composition was found to be brittle in thick plates and was not repeated in the later, thick-plate version of KC n/A (which was also never used in its non-face-hardened form). Krupp added the Molybdenum to improve ease of manufacturing (though the amount was later shown to be too much for plates of more varied thicknesses); greatly increased the metal's cleanliness (general improvement in metallurgical skill by most nations); increased the steel's toughness and overall ballistic resistance somewhat, though this form of KC n/A still could not shatter soft-capped APC projectiles (most early World War I APC projectiles other than those used by post-1908 Skoda or post-1911 Krupp APC projectiles or new post-Jutland British APC projectiles) or the new post-World War I "Hooded" Common projectiles (U.S. Navy post-World War I "Special" Common, for example) that used a soft, thin, AP-cap-like nose covering to hold the windscreen on (prevented cutting weakening threads in the hard nose); increased the average back hardness somewhat; increased the face thickness slightly to 41% of the plate; changed the hardness contour so that the hardness dropped in virtually a straight line from the back of the cemented layer to the joint of the face with the unhardened back (no separate transition layer), which significantly decreased the average hardness of the face layer compared to the older KC a/A armor, even though the surface hardness was still among the highest of all face-hardened armors; and increased the minimum thickness from 3.2" (8cm) to about 3.94" (10cm). As with KC a/A, the surface of the face was kept as hard as possible, without the small dip due to tempering that other foreign armor's had, though tempering was used quite effectively in these improved plates - tempered plates were usually hardest at about 0.25-0.5" (0.635-1.27cm) beneath the face's surface, so Krupp must have done a lot of work to prevent this surface softening. The U.S. Navy obtained secretly through Sweden some 5.12" (130mm) plates of this type in 1934 and tested them extensively in 1934-36 with AP and Common projectiles, which is where I got my plate quality figures, below.

Armor Quality

Q	QD	BLT	TC	CW	SS
0.96	Q	59	N	N	1

Usage

Vertical armor over 3.94" (10cm) on German BISMARCK Class, SCHARNHORST Class, and other projected (never-built) post-1930 battleships and battle-cruisers.

Krupp reverted back to a modified form of KC a/A for Germany's new larger warships, though retaining most of the improvements mentioned in the 'Pocket Battleship' version of KC n/A. Molybdenum was still added, but the percentage used was reduced to only 0.4% maximum by weight with the thinnest plates - same as Britain used in all of its post-1930 cemented armor (CA) - and was reduced in steps as plates got thicker to 0.22% maximum for the thickest plates. Also, a unique sliding scale for Chromium and Nickel amounts was used in this new version of KC n/A, with 2.3% of the former and 1.8% of the latter minimum in the thinnest plates (circa 3.94" (10cm)), changing step by step to 1.8% Chromium and 3.8% Nickel minimums in the thickest plates (14.96" (38 cm) and up). Note that for the thinnest plates, the composition is only slightly different from the Pocket Battleship version, while the composition of the thicker plates is very similar to most foreign post-1930 face-hardened armors, other than in their usually-different Molybdenum percentage. In addition, this form of KC n/A was finally toughened enough to shatter soft-capped APC and Hooded Common projectiles at low obliquity, as could World War II U.S. and British face-hardened armors.

However, other possible improvements were not made because Krupp was a great believer in tradition (here meaning the least possible change to improve something to the very minimum acceptable level). In fact, interviews with Krupp personnel just after World War II by the British revealed the fact that Krupp had discovered during the KC n/A improvement program that non-cemented face-hardened armor was at least as good as cemented face-hardened armor when hit by projectiles with thick, highly-hardened AP caps, which destroy the thin cemented layer well before the projectile nose gets anywhere near the plate surface (see Vickers hardened non-cemented (VH)) - virtually all post-World War I APC and SAPC projectiles had them - but continued to cement their KC n/A armor due to tradition! This was even though cementing was a very expensive and time-consuming bottleneck in face-hardened armor production - even many tank plates were given a light face-hardening treatment by Krupp, whether it helped them or not (look at the mantlet of the World War II JAGDTIGER on display at the U.S. Army's Tank Museum at Aberdeen Proving Ground, Maryland, to see what I mean). Talk about reactionary!

This improved KC n/A armor was first used in KM SCHARNHORST. The steel quality of this armor was in-between U.S. average World War II Class "A" armor and World War II British CA in thick plates with rather a small variation in overall quality (British and U.S. results matched pretty well for plates 12.6" (32cm) or more in thickness), but the thinner plates under about 28cm thick varied about 20% in quality (10% above and below the average), with some plates tested by both Krupp itself and the U.S. Navy after WWII being hardly better than the original 1894 KC a/A armor. These plates were still accepted since Krupp never seems to have changed its armor acceptance specs from the original 1894 version, though the average post-World War I KC n/A armor was obviously much better (this makes medium-thickness KC n/A armor very unreliable!!) - Krupp never changed its APC projectile acceptance spec from the 1911 version, either, though the post-1930 projectile designs were much better!!! This rather psychotic policy made Krupp armor and projectiles impossible to fail their specs virtually no matter how bad they were compared to average post-1930 metallurgical standards (being a monopoly has its advantages!), though the material made was usually better than this minimum, to be sure. During World War II alloy shortages made the amount of Chromium and Nickel in this armor go down, though by then little KC n/A armor was being made (except perhaps for repairs to KM TIRPITZ and the two SCHARNHORST Class ships).

Armor Quality

Q	QD	BLT	TC	CW	SS
0.947	Q	65	N	N	1

Usage

Vertical armor 3.2" (8cm) and up.

The firm of Witkowitz was the only Austro-Hungarian armor producer through the end of WWI and originally made a KC armor identical to Krupp KC a/A, but some time prior to 1911 (circa 1908 perhaps when Skoda's projectiles were also improved), when it made the armor for the Austro-Hungarian battleships of the KuK TEGETTHOFF Class, up to 11" (28cm) thick, Witkowitz changed its method of armor manufacture and ended up with the best WWI-era KC-type armor that I know of, based on actual test results using Austro-Hungarian Skoda post-1908 hard-capped armor-piercing projectiles similar to the latest post-1911 German Krupp "30.5cm Psgr.m.K. L/3,4" (12" Armor-Piercing Shell with AP Cap of Total Length of 3.4 Calibers (projectile diameters)) armor-piercing projectiles - note that these Skoda APC projectiles were certified using Krupp KC a/A armor test plates, not Witkowitz KC-type armor plates.

The chemical composition of the plates is essentially identical to standard Krupp KC a/A, so the hardening process used must have been improved, probably by employing a good post-hardening tempering treatment, since Witkowitz did test its plates with capped armor-piercing projectiles and would have quickly found what everyone but Krupp did: The toughness of the face needs to be increased to get optimum performance from a German Krupp 1894-KC-type plate against capped projectiles. Also, as with Krupp's own KC a/A armor, the back layer of the Witkowitz KC-type armor was probably tougher than most other KC-type armors and allowed an even better toughening treatment of the face. Just adding a face temper did not improve any other World War I-era KC-type armor as much as the Witkowitz armor, so a combination of improved face and back treatments must have been employed, including a toughening process combined with a good post-hardening temper that prevented the face layer from prematurely cracking under initial impact shock.

This is the first completely successful "SOFTSHAT"= 1 armor, in my estimation, since contemporary U.S. Midvale non-cemented Class "A" armor, which could also shatter soft-capped projectiles at all times due to the great thickness of its hard face, had the drawbacks of a large scaling effect rendering it inferior against large projectiles and inferior performance against any size hard-capped projectiles when tested during World War II. Interestingly, when Britain needed additional armor for its warships in 1938 and 1939, Witkowitz made most of this armor and it was shipped through Germany to England, even though Germany was at that moment planning to attack Poland!

Armor Quality

Year	Q	QD	BLT	TC	CW	SS
Up through the end of 1910	0.828	Q	65	N	Y	0
1911-1918	0.850	Q	65	N	N	2
1919-1930	0.900	Q	65	N	N	2

Modified versions of Krupp KC a/A as made by British Armstrong, Vickers, Brown, etc. Somewhat softer face and back than KC a/A. Curved plates were found to be rather brittle when hit by non-penetrating German projectiles at high obliquity in World War I (this was not true of Krupp's KC a/A armor, as post-World War I British tests on BADEN proved). Slightly better than KC a/A at normal obliquity due to introduction of post-hardening temper to reduce face brittleness, which I have found is very important to optimum quality in a face-hardened plate, even more than steel quality or back layer hardness (within reason, of course) - Krupp kept testing KC a/A with uncapped projectiles through the end of World War I and never recognized the importance of a tough face when a capped projectile failed to shatter instantly on impact, as an uncapped projectile always did. Japanese VC first made in Japan under license from the British Vickers Company using its 1910 KC-type armor 'recipe' for the IJN HARUNA, IJN HIEI, and IJN KIRISHIMA, the Japanese-built sister ships of the British-built battle-cruiser IJN KONGO started in 1910 and completed in 1912. There was a distinct improvement in toughness in these armors in 1911, giving a small quality increase and a large reduction in the brittleness of the plate as indicated by the throwing of cartwheels in the earlier armors (curved plate hits mentioned above, for example) and no longer doing this in the later plates of these same armors. The new version could now also shatter the improved British post-1912 forged steel APC projectiles at normal obliquity (which U.S. late-World War I U.S. Navy Class "A" armor and Krupp KC a/A could not), but could not shatter the new U.S. Navy "Midvale Unbreakable" soft-capped AP projectiles introduced just before, during, and after World War I (see U.S. Midvale non-cemented Class "A" armor) in tests with the 12" (30.5cm) size of that projectile type in Britain during World War I.

Armor Quality

Q	QD	BLT	TC	CW	SS
0.928	Q	70	N	N	1

Usage

Vertical battleship armor over 4" (10.2cm).

Greatly improved KC-type armor. Thinnest - only 15% hard face plus a 15% transition layer - and softest (only 600 Brinell) cemented layer of any post-1930 cemented face-hardened armor, which made this armor the best of all known face-hardened armors in heavy, battleship-grade thicknesses, though rather mediocre in thin plates for cruiser protection, due to the reduction in the negative effects of scaling from increasing projectile size. This armor employed all of the metallurgical improvements mentioned for the last form of KC n/A, including use of Molybdenum, but here using the maximum possible KC n/A amount of this alloy element (0.4%) - and a constant high content of Nickel and Chromium for all plates and making the face as soft and thin as practical to improve resistance against large projectile. In addition, this form of face-hardened armor had the highest back tensile strength of any face-hardened armor ever used.

The rather low steel quality of 0.928 was due to retaining the 1919 CA plate acceptance spec - using new test projectiles only for the thickest plates - and due to the thin face possibly being too far in the direction of minimizing projectile damage in an attempt to get the toughest possible plate. This is the exact opposite of the U.S. World War II Class "A" armor acceptance spec, which (in my opinion, erroneously) required a minimum amount of projectile damage and thus needing a very thick face layer, compromising the maximum possible plate ballistic limit to obtain this dubious effect (if the projectile does not penetrate, who cares what condition it is in?). Also, British post-1930 CA had a rather large (7.5% above and below the mean) quality variation in multi-plate group "Proof of Supply" tests during and after World War II. This may be another symptom of a too-thin face, since even a small variation will have a large effect when near the minimum acceptable face thickness. However, the thin face made these plates very good against large-caliber projectiles, which is where this armor had to be good and it was.

Armor Quality

Q	QD	BLT	TC	CW	SS
0.98	Q	70 (thick plates) thru 50 (thin plates)11	N	N	12

Usage

Vertical armor over 4" (10.2cm).

Italian extreme improvement of World War I KC armor; close to the best all-round face-hardened armor ever made. Values used are averages based on one 13cm TC plate (two places on plate), which I assume is representative of plates just above this thickness down to the thinnest TC plates made, and one 28cm TC plate (two places on plate), which I assume is representative of plates just below this thickness and up to the thickest TC plates made. I assume that the properties of plates of thicknesses between these values will change from one to the other in a series of small (5% of plate thickness in regards to Back Layer Thickness Percentage, for example) steps, which I have estimated in my FACEHARD program (until better data comes along, if ever). Somewhat lower yield strength than any other improved World War II-era KC and, much like Krupp's own KC armor, a very high surface hardness. These plates are unique in that the Back Layer Thickness Percentage increases with increasing plate thickness, giving a large scaling effect much like U.S. World War II Class "A" armor in thin plates, where it helps them against smaller attacking projectiles, and a much smaller scaling effect much like British World War II CA against large-caliber projectiles, where scaling would hurt the plate's resistance. The basic plate steel quality is higher at 0.98 than British World War II CA, too, which makes it the best battleship-grade face-hardened armor made in World War II! Very well thought out. This design, combined with the specified use of spaced decapping plates in the armor belt, indicates that Italian naval armor design was very advanced and second to none. First used on reconstructed Italian World War I battleships. This armor type was used for thick vertical armor on new World War II ZARA Class heavy cruisers (this extreme weight of armor was rare outside of the U.S. Navy post-1930 cruisers). These plates were tested using uncapped AP projectiles which shatter on impact, so acceptance specs are rather rough due to increased round-to-round variation. However, in the 28cm plate test a shot was accidentally fired at a much higher striking velocity than specified, so this result gave me a better clue as to plate quality.

Armor Quality

Q	QD	BLT	TC	CW	SS
0.839	Q	65	N	N	0

Usage

Vertical armor over 11" (28cm) only on the IJN YAMATO Class.

Highly modified form of Vickers cemented (VC) armor. Used 1910-spec VC deep-hardening process, but increased Carbon content to 0.5-0.55% and eliminated cementing to reduce cost so that the maximum face hardness was about 510-520 Brinell with standard heavy production plates (some experimental plates differed, as will be discussed below). Same metallurgical composition as new Vickers non-cemented homogeneous armor. This armor was unusual in that it had a 7% plate thickness layer at and just behind the plate face surface that was similar to the cemented layer of non-German KC plates, in that the hardness went from circa 450-480 Brinell at the surface (where the Carbon content also decreased due to the effects of the post-hardening temper used), increased steadily to the maximum hardness at the back (inside) edge of this region (rather deeper into the plate than with cemented armor and, of course, much softer). At this point, the hardness rapidly dropped in roughly a straight line or a "ski-slope" to the minimum face layer hardness of 350-370 Brinell (about 20 Brinell hardness points above VC) at about 18-23% of the plate's thickness from the face surface, and finally dropped more rapidly in the transition layer in another, steeper ski-slope to the back layer's usual hardness of 200-210 Brinell at the 35% plate thickness point, which is the same as in VC armor. The plate-to-plate variation in hardness pattern was remarkably small, giving a rather narrow variation in quality, though retaining the quality level of circa 1919 British CA through improved metallurgical skill - production plates still could not shatter soft-capped APC projectiles at normal, as this kind of improvement was not considered (and the armor manufacturing recipe was given to Japan prior to the major improvements in this plate quality in Britain).

Minimum production armor thickness raised to over 11" (28cm) since that was the thinnest vertical armor used in the YAMATO Class ships and maximum thickness was 26" (66cm) for turret face plates. By retaining the old Vickers water/oil quenching process on plates well above the thickness it was designed for, all VH plates in the thickness range 17-26" (43.2-66cm) did not cool fast enough deep inside and formed brittle upper bainite at their centers, which did not make them less effective as armor, but did cause them to snap in two through the impact point on any solid hit, which could result in secondary effects such as jamming turrets (the Japanese investigated the problem and solved it, but by that time no more battleships were being built).

Experimental VH plates were made by the Japanese during World War II and some of these and many production MNC, NVNC, CNC, and VH plates were brought to the U.S. Naval Proving Ground, Dahlgren, Virginia, and to the British Naval Proving Ground after the war for testing. Most of these plates, including the thick, production VH plates, showed that they were not much better than their World War I counterparts (which is not really bad for VH considering this was the best showing of any non-cemented armor actually used aboard ship and that the Japanese were not trying to make a better armor, just make British 1910-quality face-hardened armor cheaper). An experimental 7.21" (18.15cm) VH plate (#3133 at NPG, Dahlgren) seems to have been made from a German KC n/A specification added to an otherwise standard VH plate. It had a 535 Brinell maximum face hardness 3% into the plate, which is harder than all heavy VH production plate, though only by a small amount, with the hard point the closest to the face surface (about the same distance from the face surface (0.22" (0.55cm)) as with most cemented non-German KC-type plates), and a back hardness of 210-215 Brinell, which is slightly higher than production VH, but still well below average foreign World War II-era KC-type plates. The steel used was identical to the production VH plates that had been tested previously (rather dirty steel again of circa-1910 quality) and the hardness curve showed a typical VH-style pattern for the high-hardness portion. However, the major difference between this plate and all other VH plates was that the transition layer was much wider, extending to 43% into the plate (57% unhardened back), almost identical to German KC n/A, though with a higher average hardness than KC n/A in the decrementally hardened region. Since Germany and Japan were allies during World War II, it is not surprising that the Japanese may have obtained such information on German Krupp armor and made test plates to compare it with their own armor.

The U.S. test personnel at the U.S. N.P.G. did not expect it to be much different from the production VH plates, especially due to its relatively poor steel quality. However, this plate was found to be the best face-hardened plate of its thickness ever tested at the U.S. N.P.G.! (The next best plate of similar thickness was also an experimental non-cemented face-hardened plate of 7.6" (19.3cm) thickness made by Carnegie-Illinois Steel Corporation during World War II, which was only slightly inferior to this VH plate.) It required the late-World War II, improved, super-hard-capped (650-680 Brinell all the way through) U.S. 8" (20.3cm) Mark 21 Mod 5 AP projectiles to completely penetrate this plate in "effective" condition at 30° obliquity (the standard U.S. armor test in World War II) - the older Mod 3 projectiles, similar but with a maximum cap hardness of 555-580 Brinell, were torn up badly even when they completely penetrated (a rare feat against these U.S. projectiles!) and needed a much higher striking velocity to do so. Against the Mod 5 projectile, my calculations indicate that this plate was 1% better on an equivalent thickness basis than an average KC n/A plate (probably because the VH plate does not lose any resistance due to the existance of the thin, but very brittle, cemented layer used in KC n/A armor), meaning that it would take an average 7.28" KC n/A plate to replace this 7.21" VH plate - a pretty big improvement from regular VH armor in a single step! The U.S. test personnel were at a loss to explain this, but to me it seems that the Japanese personnel used the face tempering process of KC n/A, possibly with some of their own expertise added, in addition to just increasing the chill thickness. Japanese metallurgists (and most other technical personnel) obviously were (and are still) just as good as anybody else when allowed to set their own standards of excellence, as the post-World War II world has discovered big-time! Also, a rather unusual 15" VH plate was obtained by Britain at the same time and when tested showed a very high quality, also. However, this plate also had a non-cemented surface hardness of 575 Brinell, which I did not know was possible, and the British could not duplicate this plate when they tried to make two 12" (30.5cm) scaled copies in two different manufacturing plants - the plates ended up rather like improved standard production VH armor in composition and ballistic results, with only about a 500 Brinell face layer in both cases, so the British could not figure out how such a face layer was made, either.

The 26" (66cm) VH turret face plates on the YAMATO Class were inclined back 45° and were the only plates that could not be completely penetrated by any gun ever put on a warship - these plates could be holed at point blank range by a newly-lined World War II U.S. Navy 16"/50 gun with late-World War II hard-capped AP projectiles, but even these projectiles would always ricochet; the YAMATO's own 18.1" (46cm) hard-capped AP projectiles, which were designed to an only slightly-improved British circa-1921 armor penetration specification, could not even make a hole in these plates at any range, though the impacts might crack them!

Armor Quality

Year	Q	QD	BLT	TC	CW	SS
Up through the end of 1910	0.828	Q	65	N	Y	0
1911-1923	0.889	Q	65	N	Y	0

Usage

Vertical armor 4" (10.2cm) and thicker.

Average value of the armors made by the three major U.S. naval armor manufacturers of the time - Carnegie Steel Corporation (the largest), Bethlehem Steel Corporation, and the Midvale Company (the smallest) - based primarily on Carnegie Krupp Cemented (CKC), a slightly modified version of original Krupp Cemented armor, which was similar to the average KC-type armors made by the other two during this period. However, in an attempt to get more of this market, the two smaller armor manufacturers developed several radically different forms of face-hardened Chromium-Nickel-steel armor. Bethlehem introduced in several ships from 1906-1910 a form of face-hardened armor that relied completely on its deep face without the cemented layer (Bethlehem Non-Cemented Class "A" armor), which had a very large percentage of Chromium (3.5%), the largest amount of Chromium ever used, to my knowledge, and Carbon ( 0.45%) and a rather low percentage of Nickel (2.25%).

It was used as part of the armor (mixed with Midvale and Carnegie plates in a crazy-quilt pattern) in the battleships USS SOUTH CAROLINA, DELAWARE, NORTH DAKOTA, FLORIDA, UTAH, ARKANSAS, and WYOMING.

It was very brittle and many plates cracked after installation, as well as having severe face spalls (deep flaking of the surface on impact) during acceptance testing, so it was discontinued in 1910 and a CKC-like armor was re-introduced. Later testing of 12-13.5" (30.5-34.3cm) plates of this armor in 1920-21 using the new, improved 12" "Midvale Unbreakable" or "Midvale 1916" soft-capped armor-piercing projectiles showed that this armor barely met minimum specifications and had no redeeming characteristics, being noticeably inferior to average CKC 1921-time-frame plates (it was about at the original pre-1911 CKC quality). During this same time frame, Midvale also came out with its own Midvale non-cemented Class "A" armor (MNC) which had some rather unusual properties. It too was brittle (though not nearly as bad as the Bethlehem Non-Cemented armor) and it too was discontinued in 1912, after which Midvale also reverted to a CKC-like Class "A" armor.

In 1921, some problems with its armor plant, the invulnerability of the new Midvale projectiles to the CKC-type armors then in use, and the good showing of the experimental Carnegie 13" (33cm) STS plates made Bethlehem develop a unique form of cemented face-hardened armor with only a 15% face and transition layer combined, similar to a Harveyized plate, called Bethlehem thin chill Class "A" armor (BTC), also with unusual properties, that was used in some of the last U.S. battleships and in the ships canceled by the Washington Naval Treaty of 1922. It was also made by Midvale under license in 1922 and 1923. Carnegie kept making its gradually improving version of CKC.

Armor Quality

Q	QD	BLT	TC	CW	SS
0.881	Q	18	N	Y	1

Usage

Vertical armor 4" (10.2cm) and thicker.

Used as portions of the Class "A" armor of battleships USS NORTH DAKOTA, FLORIDA, UTAH, WYOMING, ARKANSAS, NEW YORK, TEXAS, and OKLAHOMA, especially 12-13.5" (30.5-34.3cm) belt armor.

Extremely constant face hardness to 25% plate depth and then a very gradual "ski-slope" hardness drop-off to the 200 Brinell level at only 18% of the plate's thickness from the back (the deepest face plus transition layer combination of any plate type that I know of). The plate used a high 0.55% Carbon to ease the hardening process somewhat, but was otherwise of more-or-less standard KC composition. The high Carbon content and the very thick hard face made these plates somewhat brittle, as noted above, but not extremely so. At the time that this armor was manufactured, it, along with rival Bethlehem Non-Cemented armor, was not considered unusual in any way ballistically. When some of this kind of armor was re-tested in 1921 using the new 12" (30.5cm) "Midvale Unbreakable" or "Midvale 1916" projectiles, which had remained unbroken in 90% of their tests at right-angles against any other kind and thickness of face-hardened armor (including World War I British KC and German KC a/A), the projectiles completely shattered, acting as if their armor-piercing caps were not there at all!

Midvale made some more plates using their old MNC recipe, but adding a cemented face layer, and got the same result, though it was found that only a specific range of heat treatment temperatures worked (this was later understood as "temper brittleness" in the 1930's when metallurgical expertise had improved). This unusual result caused Midvale to make a single lot of cemented MNC-type plates for one of the canceled warships. However, re-testing of these plates using the newer 14" (35.56cm) and 16" (40.64cm) sizes of the Midvale Unbreakable projectiles showed that the projectiles still shattered, but the improvement in resistance dropped very steeply with increasing projectile size; a huge "scaling" effect that completely nullified any ballistic improvements when the 14" projectile size was used and actually resulted in the armor being no better than Harveyized nickel-steel armor against unshattered (!!) soft-capped projectiles when the 16" projectile size was used (even with shatter occurring!). The super-thick face, which failed by fracture along surfaces, not by deformation and tearing through a volume as did ductile material, was the culprit. Needless to say, with 16" guns being used on all new U.S. battleships, Midvale had to abandon its MNC-type armor for a second time and started making Bethlehem thin chill armor under license until all heavy armor manufacture stopped in 1923.

World War II testing with the very good hard-capped U.S. 14" Mark 16 Mod 8 armor-piercing projectile type showed MNC armor to be unable to shatter these projectiles and to be very poor ballistically, in line with the poor showing of the large-caliber projectile tests of 1921. Unfortunately, the effectiveness of the very thick face of MNC armor encouraged all U.S. manufacturers to try to use a thick face (but retaining a thick back by narrowing the transition layer) against their improved post-World War I APC projectiles, which eventually proved futile, but which had the side-effect of increasing the scaling factor so that the heavier grades of World War II U.S. Class "A" armor were inferior to thinner-faced British, Italian, German, and, I assume, French face-hardened armors, though the armor steel was otherwise equal to or better than them in all other respects.

Armor Quality

Q	QD	BLT	TC	CW	SS
0.889	Q	85 (average)	Y	N	0

Usage

Vertical armor on USS WEST VIRGINIA Class (and canceled post-World War I battle-cruisers and battleships) over 4" (10.2cm).

Developed in 1921 after some problems with the manufacture of standard CKC-type Class "A" armor halted production. During this time the very good showing of the Carnegie 13" (33cm) STS plates occurred and it also became evident that the new "Midvale Unbreakable" or "Midvale 1916" armor-piercing projectiles were practically invulnerable to damage at up to 15° obliquity (the maximum obliquity test standard during this period was circa 10° for caliber-thickness armor from any nation) from any form of then-current face-hardened armor (the unusual results of the testing of Midvale non-cemented Class "A" armor (MNC) were not yet known).

It was decided by Bethlehem Steel Corporation that a better form of Class "A" armor should be developed reflecting these facts, rather than just continuing with the current very standard slightly-modified-original-KC-type armor being manufactured in the U.S. and abroad. Since the face was not working very well against the Midvale projectiles, yet at oblique impact even Harveyized nickel-steel armor would shatter them (it was not yet known that only soft armor-piercing caps were limited to 15-20° obliquity and that replacing them with hard - well over 300 Brinell at their forward surface - caps and then carefully controlling the projectile's hardness pattern could greatly expand the oblique impact ability of projectiles against even the heaviest face-hardened armor), and since Class "B"/STS armors of similar thickness were equal to or better than Class "A" armor at low obliquity (under 20° when there was no shatter) and at high obliquity (over 55° obliquity, especially when shatter occurred, which inhibited ricochet), the designers at Bethlehem simply made a normal cemented face-hardened Class "A" plate with the depth of hardened face behind the cemented surface layer reduced to only about twice as thick as the cemented layer (circa 15% of the entire plate's thickness for most plates in the 9-16" (22.86-40.64cm) range made at the time). The face was not eliminated completely since it was better than a non-face-hardened plate in the critical 20-55° obliquity region where most impacts would occur at long range due to the angle of fall if nothing else (the U.S. Navy was already specifying long-range fire supported by aircraft spotting as the "wave of the future" in naval gunnery) and since it was better against smaller uncapped projectiles under almost any conditions.

When the (short-lived) good results of the very-thick-faced MNC armor occurred and the Midvale Company made a new batch of that armor with a cemented surface, the U.S. Navy had the unusual "honor" of having both the thickest-faced and thinnest-faced forms of KC-type armor ever made, as well as a more-or-less normal KC-type armor in Carnegie's CKC, being produced for its ships at the same time! When the new MNC armor type was found to have a huge scaling effect that degraded it against larger projectiles, Midvale gave up on it and began making BTC under license.

The cancellation of all of those post-World War I battleships and battle-cruisers resulted in a very large amount of excess armor of all kinds being stored at the U.S. Naval Proving Ground in Dahlgren, Virginia, and other places. Some of it was used as experimental plates comparing improved projectiles between World War I and World War II and it was found that BTC armor made by either Bethlehem or Midvale could not damage the new hard-capped armor-piercing projectiles introduced by the U.S. during the 1920's, 1930's, and 1940's until the impact obliquity was increased to at least 40°, an obliquity well above the ability of any foreign projectiles to handle, as was determined by post-World War II testing of British, Japanese, and German projectiles of various types. However, since there were so many plates available, acceptance testing of large-caliber armor-piercing projectiles was performed using BTC plates at 40° obliquity during most of World War II, after an experimental period calibrating the damage these plates gave compared to similar plates of modern post-1930 U.S. Navy Class "A" armor, which had a very thick face, at the usual 30° obliquity (sometimes 35°).

The experience with BTC armor and MNC armor indicates to me that for significant projectile damage, a face of substantial thickness was needed, but this thickness of face must be kept at the minimum possible for thick plates to prevent excessive scaling effects, though for thin face-hardened plates - under circa 7" (17.78cm) thick - a thicker face (within reason) actually increased resistance as the scaling factor worked in reverse to benefit thin armor. Also, as U.S. MNC and Japanese VH face-hardened armors showed, the cemented surface layer was useless against high-quality, hard-capped World War II APC projectiles and should have been eliminated (saving both time and money).

Armor Quality

Q	QD	BLT	TC	CW	SS
1.00	Q	45	N	N	1

Usage

Vertical armor from 5" (12.7cm) up except for 16" (40.64cm) & up turret face (port) plates.

When U.S. naval armor again began to be developed and manufactured for new ships and for rebuilding older battleships, the lack of ability of BTC to cause enough damage to the improved U.S. hard-capped armor-piercing projectiles being developed and introduced continuously was well known, so the trend was to increase the face depth to increase the damage-causing ability of the Class "A" armor, which was already undergoing a major improvement by the increase in toughness due to better metallurgical skill in general (the new plates could shatter the now-obsolete "Midvale Unbreakable" or "Midvale 1916" projectiles (see Midvale non-cemented armor) even at right-angles, which only Midvale's unusual pre-World War I MNC armor was known to be able to do before) - German KC n/A also had a somewhat thickened face for similar reasons, though to a much lesser degree.

Unfortunately, U.S. armor-piercing projectiles just kept getting better and better, so the face thickness just kept getting thicker and thicker, until a average of about 55% of the plate was face and transition layers (35-40% face and 15-20% transition layer). Even with this level of face thickness, which was the heaviest face ever used except by MNC armor, the better U.S. armor-piercing projectiles eventually became so unbreakable that the test specifications near the end of World War II said in some cases that, if the projectile could not be damaged by the armor, do not worry about it and go on to other kinds of tests!

I know of at least one test where a U.S. 14" (35.56cm) Mark 16 Mod 8 hard-capped armor-piercing projectile (introduced in 1943 by the Crucible Steel Company, the largest and best U.S. naval projectile manufacturer for many years, and probably the best all-round naval armor-piercing projectile used during World War II) completely penetrated in effective bursting condition (no significant lower or middle body or fuze damage) a 13.5" (34.29cm) brand-new Class "A" armor plate at 49° obliquity at just above the Navy Ballistic Limit velocity, where the projectile just barely makes it through the plate and where maximum damage usually occurs to a completely penetrating projectile. (Such a result would be almost impossible to even imagine with any foreign projectile design!)

The thick face added to the scaling effect, though not nearly as much as the face of MNC had, making thick U.S. World War II Class "A" armor somewhat inferior to German KC n/A or British CA, but also working in reverse so that U.S. World War II Class "A" armor 7" (17.78cm) or less in thickness was the best face-hardened armor used by anyone ever. The replacement of Class "A" armor by Class "B" armor in the heaviest grades that were used in World War II battleship turret face plates demonstrates that the U.S. Navy was aware of the relative inferiority of its thick-faced Class "A" armor in such heavy grades against high-quality projectiles. The steel quality of this armor was equal to the best foreign armor and quality control was rather good, though Midvale armor tended to crack more than the other two manufacturers' Class "A" plates (Carnegie-Illinois Steel (later U.S. Steel) Corporation and Bethlehem Steel Corporation).